Rates of reaction Flashcards

1
Q

What are the variables that affect rates of reaction?

A

Temperature
Concentration
Surface area
Pressure

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2
Q

What has to happen for a reaction to take place?

A

Collisions with activation energy

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3
Q

What is the activation energy?

A

The lowest amount of energy that collision particles must have to react together

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4
Q

What will happen if you increase one of the variables?

A

The rate of reaction will increase as the frequency of collisions will increase

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5
Q

What happens if the concentration is high?

A

There is more particles per unit volume so there is more frequent collisions so it is faster

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6
Q

What happens if the concentration is low?

A

There is fewer particles so there is less collisions so it is slower

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7
Q

If the particles are smaller is the surface area bigger?

A

Yes as the SA:Vol is bigger

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8
Q

What happens if the surface area is bigger?

A

There is more frequent collisions so it is faster

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9
Q

What happens if the pressure is high?

A

The particles are closer together so there is more collisions so it is faster

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10
Q

What happens if the pressure is low?

A

The particles are further apart so there is less collisions so the rate is slower

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11
Q

What happens if the temperature is higher?

A

The particles have more energy so they move faster, colliding so more of these collisions have the activation energy so it is faster

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12
Q

What happens if the temperature is lower?

A

The particles have less energy so they move slower, colliding less so less of these collisions have the activation energy so it is slower

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13
Q

What is a catalyst?

A

A substance that speeds up the rate of reaction by lowering the activation energy of the reaction

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14
Q

How do catalysts lower the activation energy?

A

By providing an alternative reaction pathway

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15
Q

Are catalysts ever used up?

A

no so they can be reused

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16
Q

In reversible reactions if one way is exothermic, what will the other way be?

A

Endothermic

17
Q

What is Le Chatelier’s Principle?

A

The idea if you change the conditions of a reversible reaction at equilibrium, the system will try to counteract the change

18
Q

What can Le Chatelier’s Principle be used to do?

A

To predict the effect of any changes you make to a reaction system

19
Q

What will happen to equilibrium if you decrease the temperature?

A

It will move in the exothermic direction to produce more heat so there will be more products in the exothermic side and fewer in the endothermic

20
Q

What will happen to equilibrium if you increase the temperature?

A

It will move in an endothermic direction to decrease the temperature so there will be more products on the endothermic side and fewer on the exothermic

21
Q

What will happen to equilibrium if you increase the pressure?

A

Equilibrium tries to reduce it so moves in the direction of fewer molecules of gas

22
Q

When does changing the pressure only ever affect?

A

When an equilibrium involves a gas

23
Q

What will happen to equilibrium if you decrease the pressure?

A

Equilibrium tries to increase so moves in the direction of more molecules of gas

24
Q

What happens when you change the concentration of either the reactants?

A

The system will no longer be at equilibrium

25
Q

What will happen to equilibrium if you increase the concentration?

A

The system tries to decrease it by making more products

26
Q

What will happen to equilibrium if you decrease the concentration?

A

The system tries to increase it by reducing the amount of reactants