rates of reaction Flashcards
what is an ineffective collision
not useful as it produces no product
what is an effective collision dependent on
correct orientation (right way around)
speed (sufficient kinetic energy equal to or greater than the activation energy of the reaction)
pressure relationship
pressure is inversely proportional to volume
pressure collision theory
-a higher pressure of gas,caused by the decreased volume of a container, results in a greater number of particles per unit volume
-this causes an increase in the number of collisions between reactant particles per unit time
-and therefore there is an increase in the number of effective collisions per unit time,
-an effective collision being one that has the correct orientation + sufficient kinetic energy (Ek >= Ea)
-This leads to a higher reaction rate
surface area
outside contact points of a chemical
surface area relationship
increased surface area, more particles exposed
surface area collision theory
-an increase in surface area means a greater number of surface particles are exposed to collisions
-this causes an increase in the no. of collisions between reactant particles per unit time,
-and therefore there is an increase in the no. of effective collisions per unit time,
-an effective collision being one that has the correct orientation and sufficient kinetic energy (Ek>=Ea)
-This leads to a higher reaction rate.
concentration relationships
c=n/V
increase concentration result
there is no increase in fraction of particles in the sample with sufficient kinetic energy, equal to or greater than activation energy
There is a bulk increase in the number of particles, and therefore an increase in the number of particles capable of having effective collisions
concentration collision theory
-An increased concentration of solution leads to a greater number of particles per unit volume( c=n/v)
-this causes an increase in the no. of collisions between reactant particles per unit time,
-and therefore there is an increase in the no. of effective collisions per unit time,
-an effective collision being one that has the correct orientation and sufficient kinetic energy (Ek>=Ea)
-This leads to a higher reaction rate.
catalyst
a substance that increases the rate of the reaction but remains unchanged at the end of the reaction
ways catalyst works
-lowers activation energy
-aids correct orientation and facilitates chance of reaction
-bonds to one of reactants, changes bonding- weakens forces w/in temporary transition state, making it easier for other reactant to bond, then catalyst removed
catalyst collision theory
-a catalyst offers a reaction pathway of lower activation energy
-there is thus a greater proportion of particles w sufficient kinetic energy to overcome the activation energy (refer to maxwell -boltzman distribution curve)
-and therefore there is an increase in the no. of effective collisions per unit time,
-an effective collision being one that has the correct orientation and sufficient kinetic energy (Ek>=Ea)
-This leads to a higher reaction rate.
temperature
measure of average kinetic energy of a substance
effect of increased temp. on maxwell curve
peak decreases as bigger range of kinetic energies (increase in no. of particles w Ek>= Ea