Rate of Reactions Flashcards
What can rate of reaction be measured by?
- Vol. of gas produced per unit time
- Change in mass of reactant per unit time
What are the measuring apparatus needed to measure rate of reaction by change in mass per unit time?
stopwatch and electronic mass balance
What are the measuring apparatus needed to measure rate of reaction by vol. of gas produced per unit time?
stopwatch and gas syringe
How will the graph for rate od reaction measured by vol. of gas produced per unit time look like?
As the reaction proceeds, the volume of gas collected in the gas syringe increases
How will the graph for the rate of reaction measured by change in mass of reactant per unit time look like?
As the reaction proceeds, more gas is produced and escaped from the conical flask. Hence, the mass of the system decreases over time.
What are some interpretations of graphs regarding its gradients?
- the steeper the gradient, the faster the rate of reaction
- the gentler the gradient, the slower the rate of reaction
- When the graph is horizontal (gradient=0), the reaction has stopped.
For a chemical reaction to occur, what are the reactant particles required to do or have?
- collide with each other
- have energy equal to or greater energy than the activation energy, in order to have effective collisions and formation of products
What are factors that affect the rate of reaction?
- temperature
- size of solid reactants
- concentration
- pressure
How will size of solid reactants affect the rate of reaction?
- solid reactants with smaller particle size have higher exposed surface area
- this increases the frequency of effective collisions and hence, increases the rate of reaction
How will temperature affect the rate of reaction?
- At high temp, the particles have higher kinetic energy and collide more frequently
- more reactant particles will have energy equal to or grater than the activation energy
- this increases the frequency of effective collisions and hence, increases the rate of reaction
How will concentration affect the rate of reaction?
- at higher concentrations, particles are closer together and the no. of reactant particles per unit vol. increases
- this increases the frequency of effective collisions and hence, increases the rate of reaction