Rate of reaction Flashcards

1
Q

What is rate of reaction

A

a measure of how quickly a reactant is used up, or a product is formed

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2
Q

what are the two calculations used to measure rate of reaction

A

quantity of reactant used / time taken

quantity of product formed / time taken

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3
Q

what does the rat of chemical reaction tell you

A

how fast reactants turn into products

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4
Q

why are reactions initially fast

A

because we have a large number of reactant molecules, meaning theres a larger number of collisions per second

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5
Q

what is a successful collision

A

A collision that produces a reaction

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6
Q

what is activation energy

A

the minimum amount of energy needed for a collision to be successful

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7
Q

what does collision theory state

A

chemical reactions can only take place when the reacting particles collide with each other. the collisions must have sufficient energy

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8
Q

what is the rate of a chemical reaction determined by

A

the frequency of successful collisions

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9
Q

what effect does concentration have on rate of reaction

A

increasing concentration increases the rate of reaction,

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10
Q

why does increasing concentration increase rate of reaction

A
  • because the reactant particles become more crowded as there are more reactant particles in a given volume
  • the frequency of collisions between reactant particles increases
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11
Q

why does a higher concentration of reactant give you more product

A

because we started with more reactant molecules

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12
Q

what effect does surface area have on rate of reaction

A

increasing the surface area increases the rate of reaction

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13
Q

why does increasing surface area have that effect on rate of reaction

A

because smaller sized blocks of a solid reactant have a greater surface volume to ratio than larger blocks, this means they have more particles on the surface, meaning there are more collisions per second

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14
Q

how to investigate the effect of surface area on ror

A
  1. Use same setup and HCL and magnesium practical
    2 . Instead of mg, use a marble chip
  2. measure the volume of carbon dioxide gas produced and use it to determine the ror
  3. change the surface area of marble chips
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15
Q

effect of temperature on ror and why

A

increasing temperature increases the rate of reaction, this is because increasing temperature increases the particle’s energy
- because the particles have more energy, they move faster
- this increases the frequency of collisions and each collision has more energy
- so more particles can overcome the activation energy barrier and collide successfully

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16
Q

what are catalysts

A

things that increase the rate of chemical reaction without being used up during the reaction

17
Q

benefits of catalysts

A
  • they allow us to carry out reactions quickly without needing to increase the temperature and this saves money
  • they can be reused
18
Q

how do catalysts increase the rate of reaction

A

they provide a different pathway for the reaction that has a lower activation energy

  • They lower the activation energy. This means that more particles can successfully collide per second.
19
Q

why do we not include catalysts in a chemical equation

A

because they are not used up so they arent a reactant

20
Q

what is equilibrium

A

when reactants are placed in a place that stops reactants and products from escaping , and the forward and reverse reactions take place at the same rate

21
Q

What does Le Chatelier’s principle state

A

that if a system is at equilibrium, and a change is made to the conditions, then the system responds to counteract this change

22
Q

what happens in a reaction that is exothermic

A

temperature if system increases

23
Q

what happens in a reaction that is endothermic

A

temperature of system decreases

24
Q

what happens when temperature is increased in an equilibrium

A

the equilibrium shifts to whichever reaction is endothermic, as energy is taken in, which will cause the temperature to fall

25
Q

what happens when temperature decreases in an equilibrium

A

the equilibrium shifts to whichever side of the reaction is exothermic, as energy is released, causing the temperature to increase

26
Q

what does the pressure of a gas depend on

A

the number of molecules

27
Q

what happens when you increase the pressure in an equilibrium

A

the position of the equilibrium shifts to the side with the smaller number of molecules

28
Q

what happens if you decrease the pressure of an equilibrium

A

the position of the equilibrium shifts to the side with the larger number of molecules

29
Q

the steeper the slope…

A

the faster the reaction

30
Q

why, gradually, does the line becomes less steep in a rate of reaction graph

A

because a lot of the reactant molecules have already reacted and turned into product, meaning there are fewer reactant molecules to collide and react

31
Q

how to determine rate of reaction using how much co2 is lost

A
  • Place the reaction on a balance
  • as co2 is produced, the mass decreases
  • this can be used to find ror
32
Q

hydrated copper sulfate can be turned into what

A

anhydrous copper sulfate, which is white, and water

  • forward reaction is endo
33
Q

what is a hypothesis

A

a proposal that could explain a fact or an observation