Rate equations Flashcards

1
Q

What is the equation for rate of reaction?

A

change in concentration/ time

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2
Q

What is order?

A

the contribution of each species to the rate of reaction

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3
Q

What is zero order?

A

Rate is unaffected by changes
- as concentration changes rate stays the same

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4
Q

What is first order

A

As concentration changes by a factor the rate changes by the same factor

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5
Q

What is second order?

A

As the concentration changes by a factor the rate changes by that factor squared

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6
Q

What is the rate equation?

A

rate = k[A]^m[B]^n

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7
Q

What is the overall order

A

the sum of all orders (m+n)

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8
Q

what are the units for rate of reaction?

A

mol dm^-3 s^-1

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9
Q

What is the rate constant (K)?

A

it relates the reactant concentrations to the rate (at a particular temperature)

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10
Q

What is the relationship between the rate and K?

A

as the rate increases so does K
(the larger the K value the faster the reactiona

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11
Q

What is the relationship between the rate and K?

A

as the rate increases so does K
(the larger the K value the faster the reactiona

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12
Q

In a mechanism what is the catalyst?

A

used up in one step and re-made in a latet step

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13
Q

In a mechanism what is the intermediate?

A

Made in one step then used up in a later step

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14
Q

what is the the determining step?

A

the slow step

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15
Q

What does a Zero order time graph look like?

A

Straight line

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16
Q

What does a first order time graph look like?

A

has a curve
(bc rate change is equal to concentration change)

17
Q

What does a second order time graph look like

A

curve

18
Q

What is the Arrhenius Equation?

A

k= Ae ^ -Ea/RT

19
Q

What is the equation for calculating activation energy/temperature

A

Ink = In A - Ea/RT

20
Q

Formula for calculating Ea from gradient

A

Ea= - gradient x R

21
Q

How can you rewrite the Ink formula to find gradient

A

Ink = - Ea/R x 1/T + InA
| | |
y = m x + c

22
Q

How can you rewrite the Ink formula to find gradient

A

Ink = - Ea/R x 1/T + InA
| | |
y = m x + c