Alkanes Flashcards

1
Q

What is the formula for an Alkane?

A

CnH2n+2

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2
Q

What is the trend in boiling points of straight chain alkanes?

A

Increases
- as chain length increases so does surface area contact
- stronger VDW forces between molecules

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3
Q

What is crude oil?

A

a mixture consisting of mainly alkanes

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4
Q

What is distillation?

A

method that separates mixture os miscible liquids
separation is based on boiling points

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5
Q

What happens during distillation in a tower?

A
  • crude oil vapourised
  • passes tower which is hot at the bottom and cool at the top
  • vapouring rises and cools
  • molecules condense at different heights due to different boiling pts
  • higher boiling point= condenses further doen coloumn
  • produces fractions
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6
Q

What is a fraction?

A

mixture of hydrocarbons with similar boiling points

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7
Q

Why does the boiling point of alkanes increase?

A

increased mr
increased surface area contact

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8
Q

How do properties of hydrocarbons change as the chain gets longer?

A
  • more viscous
  • harder to ignite
  • less volatile
  • higher boiling point and stronger VDW
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9
Q

Why are hydrocarbons cracked?

A

to make use of larger hydrocarbons
shorter chains are higher in demand
alkanes make plastics and polymers

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10
Q

What is cracking?

A

breaking if longer chain alkane molecules into small ones
involves breaking of strong C-C covalent bonds

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11
Q

What are the conditions of Thermal cracking?

A

high temperature
high pressure

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12
Q

What dies thermal cracking form?

A

high % of alkENES and straight chain alkanes

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13
Q

What are the conditions of Catalytic Cracking?

A

high temperature
moderate pressure
ZEOLITE as catalyst

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14
Q

What is formed from Catalytic Cracking?

A

motor fuels
aromatic hydrocarbons
cycloalkanes

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15
Q

What is complete combustion

A

alkane and excess oxygen reacting with CO2

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16
Q

What is the equation for complete combustion

A

alkane + oxygen > carbon dioxide + water

17
Q

What is incomplete combustion?

A

when there is a limited supply if oxygen

18
Q

What is formed in incomplete combustion?

A

carbon monoxide OR carbon

19
Q

What is flue gas desulfurisation?

A

removes SO2 from the gases emitted from fossil-fuel power plants

20
Q

Which bases neutralise SO2 (sulfur dioxide )

A

CaO or CaCO3

21
Q

What is the equation for the neutralisation of SO2 with CaO?

A

CaO(s) + SO2(g) > CaSO3(s)

22
Q

What causes the production of Nitrogen Oxides?

A

high temperatures in engines cause nitrogen and oxygen to react

23
Q

What is the equation for the reaction if O2 and N2?

A

N2(g) + O2(g) > 2NO(g)

24
Q

What is the function of a catalytic converter?

A

to reduce the amount of CO and NO released by engines

25
Q

Why does a catalytic converter have a honeycomb structure?

A

increases the surface area and it is cost effective

its thinly coated in metal catalyst platinum/rhodium/palladium

26
Q

Why is a catalytic converter made of ceramic material

A

to withstand high temperatures inside the combustion engine

27
Q

How does the catalytic converter work?

A

dangerous polluting gases pass over the catalyst and react with each other to produce less harmful gases