rate equations Flashcards
zero order ?
changing [ reactant ] has no effect on the rate
1st order
change in [ reactant ] directly proportional to change in rate
2nd order
change in rate is proportional to change in [ reactant ] ^2
what is the area under the curve in a Maxwell Boltzmann distribution curve ?
total number of particles
if the rate equation is : rate = k[Y]^2
what’s the orders ?
2nd order w respect to Y
what is a key point that needs to happen In experiments about order
total volume must be constant
how to carry out an iodine clock initial rates practical ?
-measure known volume of reactants
-combine H2O2 , H2SO4 (H+) , starch, thiosulphate
-keep KI separate, to stop reaction from starting until ready
-mix the 2 beakers and start the timer
-stop timer when blue black colour appears
-repeat w different vol of KI - add water to keep total volume same
-calc rate = 1/ time
Arrhenius equation rearranged for Ea
Ea = RT(Lnk - LnA)
the gradient on an Arrhenius graph is what ?
the gradient is -Ea/R
(so u would x 8.31 then divide by 1000) to get Ea
what is meant by the term order of a reaction with respect to a ?
the power to which a species conc is raised in the reaction