Quiz 2 Flashcards

1
Q

The higher the reaction barrier(activation energy)

A

the slower the reaction

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2
Q

reactions at higher temperatures

A

are faster reactions becasue
* molecules colide more frequently
* molecules collide with more energy

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3
Q

Measuring intial rate

A
  • slope of line at start of reaction
    rise/run
  • 10-15% of the reaction progress
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4
Q

Average reaction rate

A

(final consentration-inital consentration)/(final time- inital time)

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5
Q

Calculating order

A
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6
Q

Zero-order rate constant unit

A

M s^-1

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7
Q

First-order rate constant unit

A

s^-1

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8
Q

Second-order rate constant unit

A

M^-1 s^-1

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9
Q

Integrated Rate Law graph
Zero Order

A
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10
Q

Integrated Rate Law graph
First Order

A
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11
Q

Integrated Rate Law graph
Second Order

A
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12
Q

mechanism of a reaction

A

the detailed stepwise process of how we get from starting materials to the products

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13
Q

Ea

A

“energy barrier to reaction”
Activation energy

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14
Q

Large Ea

A

slow reaction

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15
Q

Small Ea

A

Fast reaction

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16
Q

ΔH

A

ΔE = change in energy
product energy - reactants energy

17
Q

ΔH < 0

A

favorable reaction

18
Q

ΔH > 0

A

Unfavorable reaction

19
Q

In reactions catalysts

A

lower the activation energy (lowers hump)

20
Q
A

k= rate constant
A= frequency factor
Ea= activation energy
R= gas constant
T= temperature in kelvin

21
Q

parts of arrhenius equation

A
22
Q

calculating Ea

A

Ea= slope of equation x R

23
Q

calculating A

A
24
Q

comparing activation energy at diff temps

A