Quantum Mechanics quest Flashcards

1
Q

Emission spectra are characterized by narrow bright lines of different color T/F

A

True

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2
Q

Imagine an emission spectrum produced by a container of hydrogen gas. Changing the amount of hydrogen in the container will change the color of the lines in the spectrum T/F

A

False

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3
Q

In the previous question, changing the gas in the container from hydrogen to helium will change the colors of the lines occurring in the spectrum T/F

A

True

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4
Q

An absorption spectrum appears as a continuous spectrum interrupted by a series of dark lines T/F

A

True

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5
Q

The wavelengths of the emissions lines produced by an element are different from the wavelengths of the absorption lines produced by the same element

A

True but bad question

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6
Q

Which statement is true?

A

none of them

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7
Q

Why wrong? An atom emits light when it decays to a lower energy level

A

Electron not atom

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8
Q

Why wrong? An electron transition from the n=2 to the n=1 orbit will emit shorter wavelengths than a transition from the n=3 to the n=1

A

longer not shorter

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9
Q

Why wrong? An atom moving from the n=3 to the n=1 energy level absorbs light

A

electron not atom

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10
Q

Why wrong? An electron emits lights when it is excited to a higher energy level

A

gains not emits

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11
Q

How to draw a Bohr model

A
  1. Figure out e,n,p
  2. Put P and N in the nucleus
  3. Put electrons in rings around paying attention to how many can go in each ring
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12
Q

Spectroscopy

A

The branch of science concerned with the investigation and measurement of the spectra produced when matter interacts with or emits electromagnetic radiation

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13
Q

Continuous spectra

A

Continuous range of frequencies/wavelengths/energies of electromagnetic radiation

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14
Q

Line Spectra

A

A spectra consisting of discrete frequencies of electromagnetic radiation

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15
Q

Emission (bright line) spectra

A

Results from electrons losing energy when they move from an excited state to the ground state

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16
Q

Absorption (dark line) spectra

A

Results when electrons absorb energy to move from ground to excited state

17
Q

Bohr Model

A
  • In the late 19th century, a mathematical formula that related the various wavelengths of hydrogen emissions lines was discovered
  • Goal was to recognize that spectral lines are the result of transitions of electrons between energy levels that correspond to photons of light with an energy and frequency related to the energy spacing between levels
  • Wrong because only explains for hydrogen atom
18
Q

Light emission you can’t see

A
  1. Lyman- anything-1; ultraviolet
  2. Balmer- anything-2; visible
  3. Paschen- anything-3; infrared
19
Q

How may electrons can each ring hold?

A
  1. 2
  2. 8
  3. 18
    4-7. 32
20
Q

The Quantum Mechanics Model

A
  • The Quantum Mechanics Model describes the most likely location of an election
  • It like the address of an electron
  • There are four quantum numbers
21
Q

Louis de Broglie

A

determined electrons can act as waves

22
Q

Werner Heisenberg and Erwin Schrodinger

A

described mathematically the wave properties of electrons with the quantum theory

23
Q

Energy levels and their number of sub levels

A
  1. s
  2. s & p
  3. s, p, & d
    4-7. s, p, d, & f
24
Q

How many electrons each sub level can hold

A

s-2
p-6
d-10
f-14

25
Q

How many orientations each sub level has

A
s- 1
p- 3
d- 5
f - 7 
- Each orbital holds 2 electrons 
- Size of orbital determines which energy level its in
26
Q

Aufau principle

A
  • An electron occupies the lowest energy orbital that can receive it
  • know how to write the tree thing
27
Q

Pauli Exclusion Principle

A
  • No two electrons in the same atom can have the same set of four quantum numbers
  • In the orbital diagram, 2 electrons within the same orbital have to have opposite spins
  • Up/Down arrow in the same box
28
Q

Hunds rule

A
  • Orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron and all singly occupied orbitals must have the same spin state
  • Electrons don’t want to be with each other/double up because they have opposite spins
  • 3 boxes each with an arrow in the same direction
29
Q

How to write electron configuration

A

energy level, sub level, number of electrons, follow tree

30
Q

How to write orbital model

A

Write EL and SL and then number of orbitals with electrons to fill them

31
Q

Orbital diagram what the represent and what they’re represented by

A
  1. Energy level; state; 1-7
  2. Sublevel; city; s p d f
  3. Orbital; street; box
  4. Spin; house number; arrows
32
Q

Ions

A
  • If its +, take away electrons in orbital model and configuration
  • If its -, add to orbital model and configuration
33
Q

Energy level

A

The size of the area where the electron is found

34
Q

Sub level

A

The shape of the area where the electron is found

35
Q

Orbital

A

Orientation in space of that area the election is found

36
Q

Abbreviated configuration

A
  • AKA nobel gas configuration
  • Find nobel gas (last column) with the closest (but lower) number of electrons, write that, then the rest of the configuration
37
Q

Excited if

A

It doesn’t follow the tree order