Quantative Chemstry Flashcards

1
Q

1 mole

A
  • mol

- Avagadro number of particles in a substance

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2
Q

Avagadros number

A
  • one mol

- 6.02x 10^23 atoms

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3
Q

Mol

A

Mass/mr

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4
Q

Atomic number

A

Number of protons or electrons

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5
Q

Mass number

A

Number of protons and neutrons

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6
Q

Isotypes

A
  • Atoms of the same element
  • same atomic number- same number of protons
  • diff no. Neutrons (diff mass number)
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7
Q

How to calculate mass of product/reactant of reaction

A
  • balanced equation
  • find ratio between products/reactants
  • find mr of chemicals interested in
  • calculate no. Mole from chemical given mass
  • use ratio to calculate no. Mol in other chemicals
  • calculate mas from mol
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8
Q

How to balance equations from given masses

A
  • calculate mol from given mass
  • divide : no mol of each substance/smallest no of mol in reaction
  • make ratio from this
  • implement into balanced symbol equation
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9
Q

Limiting reactant

A
  • in a chemical reaction w/ two reactants, common to use an excss of one of the reactants to ensure all of the other is used
  • reactant that is completely used up is the. Limiting reactant
  • limits amount of product that can be made
  • amount of product fromed is directly proportional to amount of limiting reactant
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10
Q

Relative formula mass (definition)

A

Sum of relative atomic masses of the atoms in the numbers shown in the formula
-mr

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11
Q

Relative atomic mass

A
  • average mass of all diff isotypes of an element
  • ar
  • (ar x abundance)/number of isotypes(100)
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12
Q

Atom “ economy

A

Mr of desired product x 100 / mr of all reactants

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13
Q

Percentage purity

A

Mass of pure product x 100/ actual mass

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14
Q

Concentration

A
  • amount of mol of solute in a given volume of solution

- mol/dm3

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15
Q

Volume of gas - at 20C and 1atm

A

24 x mol

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16
Q

How to find the conc of other solution

A
  • find mol of other solution:
    • mol=conc x vol
    • use ratio to find mol of other solution
17
Q

Standard solution

A

Has an accurately known conc

18
Q

Percentage yield

A

Actual mass of product x 100 / max mass of product

19
Q

0% percentage yield

A

No product made

20
Q

Why is percentage yield not 100%

A
  • reaction may not go to completion because its REVERSABLE
  • some of product may be lost when its SEPERATED from the reaction mixture
  • may react in a diff way to expected reaction
  • evaporation
  • not all reactants react to make products
21
Q

How to find percentage yield

A
  • find mr
  • work out mass theoretical mass
    • Mr x n of molecules eg. 2Cl = x2
    • divide this number by no. Mr of reactants
    • times result by theoretical mass eg. 50g = x50
  • use formula
22
Q

Percentage by mass

A

Mr of element x 100 /mr of compound

23
Q

Converting from mol/dm3 -> g/dm3

A

Conc (mol/dm3) x mr

24
Q

Molar vol of gases

A

Equal amounts of moles of gases occupy same volme under same conditions of temp and pressure

25
Q

Mol of gas (equation)

A

Vol(dm3)/24dm3. = vol(cm3)/24 000cm3

26
Q

How to calculate mass of gas

A
  • calculate no. Of mol
  • find molar ratio
  • find mol of gas
  • find mass =mr x mol =g
27
Q

Atom economy (utilisation)

A
  • measure of amount of starting materials that end u as desirable product
  • used for sustainable development
  • used for economic reasons -use reactions w/ high atom economy
28
Q

Why is a particular reaction pathway used?

A
  • atom economy
  • yield
  • rate of reaction
  • equilibrium position (how stable/easy to push one way)
  • usefulness of by-product
  • cost of materials, heat, pressure
  • safety (high pressure/toxicity)
  • sustainability (crude oil)
  • availability
  • waste disposal
  • pollution
  • energy requirements