8-purity, Formulations, Chromatography Flashcards
Lithium flame test
Crimson (red) flame
Sodiium flame test
Yellow flame
Potassium ion flame test
Lilac flame
Copper ions (+2) flame test
Green flame
Copper (+2) sodium hydroxide added
Blue precipitate- copper hydroxide formed
Calcium ions
Flame test-orange-red flame
Sodium hydroxide- white precipitate which does not dissolve when more sodium hydroxide added
Magnesium ions +sodium hydroxide
White precipitate which does not dissolve when more sodium hydroxide is added
Aluminium ions and sodium hydroxide
White precipitate which dissolves when more sodium hydroxide is addedd
Iron(II) ions and sodium hydroxide
Green precipitate - iron hydroxide
Iron (III) and sodium hydroxide
Brown precipitate-iron hydroxide
How to test for carbonate ions CO3 2-
Dilute acid- bubbles of gas, that would turn limewater cloudy
Barium chloride with hydrochloric acid/silver nitrate with nitric acid- bubbles of gas when acid added
How to test for sulfate ions SO4 2-
Forms white precipitate when barium chloride with hcl added (barium sulfate formed)
How to test for chloride ions
White precipitate formed when silver nitrate with nitric acid is added (silver chloride)
How to test for bromide ions
Cream precipitate formed when silver nitrate with nitric acid is added (silver bromide)
How to test for Iodide ions
Yellow precipitate formed when silver nitrate with nitric acid is added (silver iodide)
Crimson (red) flame
Lithium ion flame test
Yellow flame
Sodium ions flame test
Lilac flame
Potassium ions flame test
Green flame
Copper 2+ ions flame test
Orange-red flame
Calcium 2+ ions
White precipitate which does not dissolve when more sodium hydroxide is added
Calcium ions (but can check with orange-red flame) or magnesium ions
White precipitate which does dissolve when more sodium hydroxide added
Aluminium ions
Green precipitate
Iron (II) ions when sodium hydroxide added
Brown precipitate
Iron(III) ions with sodium hydroxide
Dilute acid added and bubbles of gas which turn limewater cloudy are produced
Carbonate (CO3 2-) ions
Barium chloride with hcl form white precipitate formed
Sulfate so4 2- ions
Silver nitrate with nitric acid -white precipitate formed
Chloride ions
Silver nitrate with nitric acid-cream precipitate
Bromide ions
Silver nitrate with nitric acid- yellow precipitate
Iodide ions
Flame emission spectroscopy
- example of aninstrumental method used to analyse metal ions in solution
- sample put it a flame
- light given out
- passed thorugh spectroscope
- out put line specimin
- analysed to -identify metal ions ina solution
- measure their conc
- analysed to -identify metal ions ina solution
Chemical methods
Resulsts chemical reactions
Eg/. Chemical methods
- flame tests
- adding reagants to give precipitates
Pros of chemical methods
Often simple to do
Cons of chemical methods
Uses up sample
Pros of instrumental methods
- small sample used
- cost
- accurate
- gives lots info
- sensitive
Cons of instrumental methods
-machines;instruments can be expensive
Identification of hydrogen
Burning splint held at the open end of a test tube of the gas
Hdrogen burns rapidly with a pop sound
Identification of oxygen
-glowing split inserted into a test tube of the gas relights in the presence of oxygen
Identification of co2
- aqueous solution of calcium hydroxide(lime water)
- when co2 is bubbled through it- turns cloudy/miilky
Identification of chlorine
-damp litmus paper put in chlorine gas, litmus paper is bleached and turns white
Solute
Soldi that dissolves into the solvent
Solvent
The liqy=uid that solute dissolves into
Solution
A solute and solvent mixed together
Formulation
-a mixture which has a purpose
0mixture must be in fixed proportion
-eg. Fuels, cleaning agent, paints
Pure substance
- single element or compound
- not a mixture
- eg. Pure milk
- melting and boiling point can distinguish pure substanceds from mixtures
Precipitates
-insoluble product that forms when two solutions are mixed and react together
Chromatography
- as solvent moves up paper it takes solute
- dont use wateer as too polar
- solute dissolves into solvent
- solute moves in and out of mobile and stationary phase
- distance moved by solute depends on solubility and attractive forces between solute and chromatography paper
Rf value
- quantative approach
- d by solute/d by solvent
Why does pure substances look like
Single spot in all solvents
What are the uses of chromatography
- seperating mixtures
- help identify substances
Why some spots may not be seen
- components are colourless in solution
- dyes/chemicals same rf value
Flame tets
- used to identify osme metal ions (cations)
- if sample containing a mixture of ions is used
- some flame colours may be mixed
Metal hydroxides
- used to identifysome metal ions
- when mixed with metal ions- insoluble hydroxide precipitate may be producedd
Carbonates
- dilute acids + carbonate ——> co2
- co2 tested with limewater
Halides test
Halide ions + silver nitrate solution+ dilute nitric acid
-forms precipitate
Sulfates test
Sulfate ions + barium chromium solution + HCL
-white precipitate