Quantam Mechanics Flashcards
A new model
The Rutherford model did explain what kept the -e’s from crashing into the the nucleus
ground state
the normal configuration for an atom. all e-s are at their lowest possible energy state
Exited state
when energy is added to an atom through heat or electricity some electrons jump up to higher energy levels
absorption
when electrons go into higher levels but don’t stay there
emission
when the electrons go back to the ground state and it releases energy. and it does this in the form of light. we call this a photon
What kind of wave is light
electromagnetic wave
spectrum of light
radio, microwave, infrared, visible, ultraviolet, x-ray, gamma ray
radio is the largest wavelength, gamma is the smallest,
radio has the least hertz gamma and the most
how fast do electromagnetic waves travel
2x10 to the power of 8 m/s
wavelength
the distance from crest to crest or trough to trough (measured in nm)
frequency
the number wave lengths that pass per second (hertz- hz)
what is the formula for speed
speed= wavelength x frequency
c = λf or v
c= speed of light (m/s) λ= wavelenght n/m f or v= frequency
formula for the speed of a wave
Werner heisenberg= Particles behave like waves
showed that we could not know the speed and location of e’s at the same time (uncertainty principle)
Erwin shrödinger= Particles behave like waves
came up with the equation to show where the electrons could be along paths called wave functions
what does light behave like
light can also behave like a particle as it does in the photoelectric effect but it can also behave like a wave
photoelectric effect
when the light of certain frequencies shines on a metal, electrons are emitted
what did Albert Einstein win his award for
the photo-electric effect
Quantum Numbers
a set of 4 characters that describe the properties of each electron (every electron has its own 4-character code)
Orbital
an orbital is a 3-dimensional space around the nucleus that indicates the location of an e 90% of the time
Principal quantam number (1)
-symbolized by n=1,2,3 etc…
-indicates the main energy level
-occupied by the e (also called the shells)
-as n increases distance from the nucleus increases
azimuthal quantam number(2)
- symbolized by l=s,p,d,f or g hypothetically
-indicates the shape of the orbital
-different orbitals within the same energy levels called sublevels
-the max number of sublevels (orbital shapes) in an energy level equals the principal quantum number n
Magnetic quantum number (3)
-within sublevels, these are the orbitals
-indicates the orientation of the orbital around the nucleus
-each orientation can hold two e’s
-there are n squared orbitals per energy level
what does the s orbital look like
a circle
what does the p orbital look like
two ovals coming out from the center