Quantam Mechanics Flashcards

1
Q

A new model

A

The Rutherford model did explain what kept the -e’s from crashing into the the nucleus

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2
Q

ground state

A

the normal configuration for an atom. all e-s are at their lowest possible energy state

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3
Q

Exited state

A

when energy is added to an atom through heat or electricity some electrons jump up to higher energy levels

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4
Q

absorption

A

when electrons go into higher levels but don’t stay there

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5
Q

emission

A

when the electrons go back to the ground state and it releases energy. and it does this in the form of light. we call this a photon

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6
Q

What kind of wave is light

A

electromagnetic wave

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7
Q

spectrum of light

A

radio, microwave, infrared, visible, ultraviolet, x-ray, gamma ray
radio is the largest wavelength, gamma is the smallest,
radio has the least hertz gamma and the most

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8
Q

how fast do electromagnetic waves travel

A

2x10 to the power of 8 m/s

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9
Q

wavelength

A

the distance from crest to crest or trough to trough (measured in nm)

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10
Q

frequency

A

the number wave lengths that pass per second (hertz- hz)

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11
Q

what is the formula for speed

A

speed= wavelength x frequency

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12
Q

c = λf or v

A

c= speed of light (m/s) λ= wavelenght n/m f or v= frequency
formula for the speed of a wave

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13
Q

Werner heisenberg= Particles behave like waves

A

showed that we could not know the speed and location of e’s at the same time (uncertainty principle)

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14
Q

Erwin shrödinger= Particles behave like waves

A

came up with the equation to show where the electrons could be along paths called wave functions

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15
Q

what does light behave like

A

light can also behave like a particle as it does in the photoelectric effect but it can also behave like a wave

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16
Q

photoelectric effect

A

when the light of certain frequencies shines on a metal, electrons are emitted

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17
Q

what did Albert Einstein win his award for

A

the photo-electric effect

18
Q

Quantum Numbers

A

a set of 4 characters that describe the properties of each electron (every electron has its own 4-character code)

19
Q

Orbital

A

an orbital is a 3-dimensional space around the nucleus that indicates the location of an e 90% of the time

20
Q

Principal quantam number (1)

A

-symbolized by n=1,2,3 etc…
-indicates the main energy level
-occupied by the e (also called the shells)
-as n increases distance from the nucleus increases

21
Q

azimuthal quantam number(2)

A
  • symbolized by l=s,p,d,f or g hypothetically
    -indicates the shape of the orbital
    -different orbitals within the same energy levels called sublevels
    -the max number of sublevels (orbital shapes) in an energy level equals the principal quantum number n
22
Q

Magnetic quantum number (3)

A

-within sublevels, these are the orbitals
-indicates the orientation of the orbital around the nucleus
-each orientation can hold two e’s
-there are n squared orbitals per energy level

23
Q

what does the s orbital look like

A

a circle

24
Q

what does the p orbital look like

A

two ovals coming out from the center

25
Q

what does the d sublevel look like

A

clover leaf with the ovals

26
Q

what does the f sublevel look like

A

six ovals coming out of the center

27
Q

Spin Quantum number (4)

A

-has only two possible values 1/2 or negative 1/2
-indicated the directions of the spins
a single orbital orientation has the ability to hold a max of two e’s which must have opposite spins

28
Q

what is the electron configuration

A

arrangement of electrons in an atom

29
Q

why are atoms lazy

A

they want to be in the lowest energy state possible

30
Q

ground state electron configuration

A

this is the lowest energy arrangement of electrons for each element

31
Q

three rules that govern electron placement

A

Aufbau principle
Hunds Rule
Pauli Exculsion Principle

32
Q

Aufbau Principle

A

an electron occupies the lowest energy orbital that can receive it (lowest energy first)

33
Q

Hunds Rule

A

orbitals of equal energy are each occupied by 1 electron of the same before any orbital is occupied by a 2nd electron

34
Q

Pauli Exclusion principle

A

no two electrons in the same atom can have the same set of 4 quantum numbers (opposite spins) no two electrons can have the same numbers

35
Q

electromagnetic radiation

A

Electromagnetic radiation in chemistry refers to energy that travels through space in the form of waves, which include visible light, ultraviolet, infrared, and other forms of radiation. c=λ⋅ν

36
Q

Electromagnetic Spectrum

A

refers to the entire range of electromagnetic radiation which is categorized by wavelength or frequency that can interact with matter.

37
Q

Interference pattern

A

refers to a pattern of light or other waves that occurs when two or more waves overlap and combine. this is a result of wave interference

38
Q

Emission spectrum

A

refers to the range of wavelengths of light emitted by atoms or molecules. it is unique for every element because every element has a different electron configuration

39
Q

Heisenberg uncertainty principle

A

In chemistry, it helps explain electron behavior and atomic orbitals. it talks about how it is impossible to know the position and momentum of a particle (like an electron) at the same time

40
Q

orbitals

A

a region where the atom is 90% of the time. (s,p,d, and f) base on the mathematical equation that schrödinger did which describes the wave-like behavior of electrons

41
Q

what did Schrödinger do for this

A

The Schrödinger equation explains the quantization of energy levels in atoms. It is fundamental to understanding the electron configurations in atoms and how electrons occupy specific orbitals.