post lab discussion 1 & 2 - acid rain Flashcards
it is an acidic precipitation
(examples)
acid rain
(rain, snow, fog, sleet, dry particles of dust that fall from the sky)
what does rainwater composed of
chemicals
particulates (Mg, K, Ca, Na & CO2)
H2O + CO2
H2CO3 - carbonic acid (pH 5.6)
what reaction increases its acidity to pH
oxides of nitrogen and sulfur dioxide
increase its acidity to pH 4.0 - 4.3
oxides of nitrogen and sulfur dioxide occurs naturally as short-lived by products of ____ and ____
volcanic eruptions
lightning
NOx -
SO2 -
NOx - oxides of nitrogen
SO2 - sulfur dioxide
what causes the increase of the amount of NOx and SO2
burning of fossil fuels from powerplants (electricity), refineries (oil and gas) and automobiles (vehicles)
equations of
formation of sulfuric acid from burning coal and
formation of nitric acid from internal combustion engines burning gasoline and diesel fuel
formation of sulfuric acid from burning coal
S2 + O2 —-> SO2
SO2 + O2 —–> SO3
SO3 + H2O —–> H2SO4
formation of nitric acid from internal combustion engines burning gasoline and diesel fuel
NO + O2 —-> NO2
NO2 + H2O —–> HNO3
briefly explain the acid rain in Adirondack Park
in the 1960s, power plants in the Midwest that burned coal were causing air pollution probs locally
to address: EPA - Environmental Protection Agency advised to build very tall smokestacks around 70-80 storied high - carry pollution away from local area
however, it disperse the pollution to other states. damaging lakes, rivers and forest in parks
Adirondack Park was created by …
the Eastern upstate New York in 1982
one of the 1st forever wild forest preserves in the nation
Adirondack Park has a vast wilderness area
6 million acres that is bigger than the combined of Yellowstone, Yosemite, glacier and grand canyon national park [YYGG]
It has a diverse mountain landscape, clean waterways, boreal forests and towering mountains.
Adirondack Park
effects of acid rain in Adirondack Park
accelerates weathering in metal and stone structures
acidification of bodies of water
mercury toxicity
leaching of soil constituents
aluminum toxicity
existence of black file
briefly explain the effects of acid rain: accelerates weathering in metal and stone structures
acid in the rain causes weathering and wear and tear on metal, stone, and other materials used in historic buildings and monuments
how many lakes and ponds are already acidic to support the plants and aquatic wildlife
500 lakes and ponds out of 2800
what could acid rain could contain which makes the poisonous
metal ions
Fe, Mn, Cu, Pb, Zn
briefly explain the effects of acid rain: acidification of bodies of water
acid rain makes the water in lakes and ponds more acidic. This kills off many plants and animals that can’t survive in acidic water, disrupting the entire ecosystem
loss of fish and wildlife: the acidic water contains high levels of toxic metals like lead and copper, which poisons and kills off fish, frogs, and other aquatic life. many species that used to be common in the lakes have disappeared
briefly explain the effects of acid rain: of lead and copper
lead - highly toxic to humans
copper - kills the beneficial bacteria that allow septic system to break down wastes and purify water systems
briefly explain the effects of acid rain: mercury toxicity
when acid rain falls, it helps release mercury release into the air then deposited into remote forested areas
once in the enviro, converted into methylmercury. it absorbed into tissue of animals and plants
(from inorganic Hg to organic Hg/ methylated mercury)
briefly explain the effects of acid rain: leaching of soil constituents
The acid rain leaches away important nutrients like calcium and magnesium from the soil, weakening and killing trees. It also makes the soil more toxic with high levels of aluminum.
declines growth rates and unexpected death of trees in Hubbard Brook Forest
what species at Big Moose lake has been exterminated due to acid rain
&
what animals are rarely seen
exterminated due to acid rain:
trophy- sized brook trout
white fish
landlock salmon
lake trout
rarely seen:
frogs
freshwater shrimp
crayfish
hooded mergansers
otters
briefly explain what Covewood Lodge owners Diane and C.V. “Major” Bowes was surprised about
water contaminated 5 times as much as lead and copper that were leached out of the inside pipes and plumbing fixtures
which reservoir/ lake has been found to have substantial mercury contamination
Cranberry lake
Stillwater reservoir