Polyprotic-Acids and Bases Flashcards
What is a polyprotic acid?
Polyprotic acids are acids that contain more than one ionizable hydrogen atom. Sulfuric acid is an example of a diprotic polyprotic acid.
Describe the stepwise dissociation of a diprotic acid?
The dissociation of diprotic acids occurs in two steps;
- the first step is when the first proton is transferred to a different atom.
-The second step is when the second proton is donated to another atom.
Explain how the pH changes with each dissociation step in polyprotic acids
The weak polyprotic acid dissociates, the proton (H+) combines with H2O to form H30+. The concentrations of both A- and HA are equal, therefore [A-] [HA] = 1, pH = pka + log(1)
What is a polyprotic base and how does it differ from a polyprotic acid?
Polyprotic acid and base they can donate or accept more than one proton
Provide an example of a polyprotic base and its reaction in water
Ammonium hydroxide is dissolved in water; NH4OH + H2O –> NH4 + OH-