Polymers Flashcards
Two types
addition condensation
bonding in addition polymers
VDW between molecules
are addition polymers biodegradable
no due to the non-polar covalent bonds. not susceptible to attack by nucleophiles
disposal of poly(alkenes)
can be burnt to produce CO2 and water to produce energy
Condensation polymers formed from
monomers with functional groups at both ends
condensation polymers formed by
two molecules joining together, eliminating a small molecule (usually water)
methods to make polyesters
diacid + diol (removes water)
diacyl chloride + diol (removes HCl)
Terylene
benzene-1,4-dioic acid + ethene-1,2-diol
Polyamides
diacid + diamine (removal of water)
Nylon-6,6
hexandioic acid + hexane-1,6-diamine
Kevlar
benzene-1,4-diamine + benzene-1,4-dioic acid (removal of water)
use for kevlar
bullet proof vests
memorised polymers
terylene, nylon-6,6 , kevlar
use for polyesters and polyamides
high strength synthetic fibres
bonding in polyamides
hydrogen
are polyesters and polyamides biodegradable
yes because they’re polar molecules so can be attacked by nucleophiles