Polymerisation Flashcards
Most common way of making polymers
radical polymerisation
2 types of radical polymerisation?
emulsion polymerisation and suspension polymerisation
Emulsion polymerization (EP) is a way of polymerizing
hydrophobic monomers in water
Chemical initiator used for hydrophobic monomers in homogeneous polymerisation.
AIBN: azoisobutyronitrile (hydrophobic)
Chemical initiator used for hydrophilic monomers and emulsion polymerization
KPS: potassium persfulfate (hydrophilic)
Define Propagation
polymers forms by the successive addition of free-radical building blocks
Types of radical addition
primary radical addition, monomeric radical addition, polymeric radical addition.
2 types of deactivation by termination
combination, disproportionation
which reaction of is favoured if not sterically hindered?
combination.
define deactivation
stop macromolecules from growing infinitely big.