Fragrance functional groups Flashcards
Define terpenes
hydrophobic hydrocarbon s built off 5 carbon isoprene units
Define terpenoids
derived from terpenes but contain oxygen groups
how many isoprene units in a monoterpene?
2
how many isoprene units in a diterpene?
4
most important terpene in perfume family?
oxygenated monoterpenes
Lavender terpene?
linalool
natural fragrances more likely to only be
only one isomer
list 5 key monoterpenes
geraniol/nerol, linalool, citronelol, citronelal, citral
list 2 feedstocks for monoterpenes?
wood pulp by products, petroleum industry sources
monoterpene stability issues due to..
double bonds
functional group on citronelal?
aldehyde
functional group on citronelol?
alcohol
Functional group on geraniol?
alcohol
Functional group of citral?
aldehyde
names of 2 citral isomers?
geranial (E trans) and neral (Z cis)
list 3 important cyclic monoterpenoids
carvone, terpineol, menthol
what smell is associated with R- limonene?
citrus oranges/limon
what smell is associated with S- limonene?
Piny/minty
what smell is associated with R-(–)-carvone?
sweetish minty smell
what smell is associated with S-(+)-carvone
spicy aroma with notes of rye
What is has a greater environmental impact; menthol extracted from crop or synthetic from fossil fuel?
extracted from crop.