Physics #3 Flashcards

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1
Q

the zeroth law of thermodynamics

A

2 objects in thermal equilibrium will not participate in heat exchange.

Also, if a=b and b=c then a=c.

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2
Q

at the molecular level, temperature if proportional to the _______

A

average kinetic energy of the particles that make up the substance.

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3
Q

thermal equilibrium occurs when ____ heat is transferred between two objects in thermal contact

A

no

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4
Q

the third law of thermodynamics

A

the entropy of a perfectly organized crystal at absolute zero is 0.

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5
Q

how does a material’s linear expansion coefficient compare to its volumetric expansion coefficient?

A

Beta = 3xalpha

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6
Q

is there a maximum distance at which thermal contact does not exist?

A

no, thermal contact will always exist no matter how far apart two objects are. It might just be very very miniscule at large distances.

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7
Q

compare the length change of 2 objects that differ starting lengths but increase temperature the same

A

the object that was longer to start will undergo a greater change in length (formula)

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8
Q

accuracy is related to an ____, not a scale

A

instrument

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9
Q

isolated system

A

cannot exchange energy or matter with the surroundings

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10
Q

in an isolated system, internal energy change = ___

A

0

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11
Q

____ are thermodynamic properties that are a function of only the current equilibrium state of a system, while ____ describe the path taken to get from one state to another

A

state functions

process functions

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12
Q

list the state functions

A

pressure, volume, density, temperature, enthalpy, internal energy, gibbs free energy, entropy

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13
Q

list the process functions

A

heat and work

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14
Q

first law of thermodynamics

A

internal energy conserved

mechanical energy conserved when no nonconservative forces present

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15
Q

what can lead to an increase in the internal energy of a system

A

increase in heat or work done on the system.

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16
Q

second law of thermodynamics

A

objects in thermal contact and not in thermal equilibrium will exchange heat energy such that the object with the higher temperature will give off heat energy to the object with a lower temperature until both objects have the same temperature at thermal equilibrium

energy is spontaneously dispersed from being localized to becoming spread out of it is not hindered from doing so.

the energy of the universe is increasing

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17
Q

what is heat?

A

the process by which a quantity of energy is transferred between two objects as a result of a difference in temperature.

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18
Q

describe conduction

A

need direct physical contact: kinetic energy is transferred from particles of the hotter matter to particles of the cooler matter

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19
Q

describe convection

A

the transfer of heat by the physical motion of a fluid over a material

20
Q

describe radiation

A

transfer of energy by electromagnetic waves

21
Q

only ____ and _____ can transfer heat by convection

A

liquids and gases

22
Q

which type of heat transfer does not need matter to transfer heat?

A

radiation

23
Q

define the specific heat of a substance

A

defined as the amount of heat energy required to raise 1 g of a substance by one degree Celsius.

24
Q

will the temperature of a substance start to increase before all of the solid is changed to liquid?

A

no, all solid must be changed to liquid before the substance will begin to rise in temperature.

25
Q

phase changes are related to changes in ______ not kinetic energy

A

potential energy

26
Q

liquid water and ice have the _______ kinetic energy at the same temperature

A

same

27
Q

solid to liquid

A

melting/fusion

28
Q

liquid to gas

A

vaporization/evaporation/boiling

29
Q

what is another word for melting

A

fusion

30
Q

gas to liquid

A

condensation

31
Q

liquid to solud

A

freezing or solidification

32
Q

solid to gas

A

sublimation

33
Q

gas to solid

A

deposition

34
Q

what is the name of the heat of transformation for solid to liquid/liquid to solid

A

heat of fusion

35
Q

what is the name of the heat of transformation for liquid to gas or gas to liquid

A

heat of vaporization

36
Q

the heat of fusion represents how much heat is require to _____

A

completely melt a substance of some mass.

37
Q

for a closed loop process, how do you calculate the work done

A

work is a process function so it is path dependent so you can look at each step.
overall, you will simply take the area within the curve of a pressure-volume graph.

38
Q

entropy

A

the spontaneous dispersal of energy at a specific temperature

39
Q

what are the units for entropy

A

J/(mol)(K)

40
Q

calorimeters are attempts at ____ systems

A

isolated

41
Q

1 degree celsius is equal to _____ degrees Farenheit

A

1.8

42
Q

1 degree celsius is equal to _____ degrees Farenheit

A

1.8

43
Q

when calculating the work from a pressure volume graph loop, a loop in the clockwise direction does _____ work on the environment

A

positive

44
Q

_____ are our best approximations of isolated systems

A

calorimeters

45
Q

convection requires ____ of a fluid

A

flow

46
Q

According to the second law of thermodynamics, the overall entropy change of a system ______ in a thermodynamic process that moves from one equilibrium state to another

A

can never be negative