Physics Flashcards
what is the type of weaker force that liquid molecules exert BETWEEN/ON each other
van der waals forces
what is the pressure exerted by a vapor when, at any one temperature, an equilibrium is reached at which the same number of molecules are vaporizing as are returning to liquid
saturated vapor pressure
only within a closed container**
The temperature at which vapor pressure becomes equal to atmospheric pressure and at which all liquid changes to gas phase
boiling point
The higher the boiling point, the greater the chance it will be ___?
liquid
it takes longer to reach a gas phase
how are saturated vapor pressure and boiling point related?
inversely
The lower the boiling point, the higher the vapor pressure.
as temperature rises, does vapor pressure increase or decrease
increase
(think, boiling point decreases the hotter it gets)
Is vapor pressure a function of volume, temperature or pressure?
temperature
what is the equation for force? newton’s second law?
Force= mass x acceleration (F=ma)
what is the force applied over a surface
pressure
what is the equation for pressure
Pressure=force/area
what is the pressure of 1 newton acting over 1 square meter – N/m2
pascal (Pa)
however, kPa is usually used
what is atmospheric pressure (ATM) in bar?
1 bar
what is atmospheric pressure (ATM) in kPa?
100
what is atmospheric pressure (ATM) in mmHg?
760
what is atmospheric pressure (ATM) in cmH2O?
1034
what is atmospheric pressure (ATM) in psi?
14.7
what is 1kPa in mmHg?
7.5*****
what is 1kPa in cmH2O?
10.34
what is 1kPa in psi
0.147
what is gauge pressure + atmospheric pressure
absolute pressure
when an oxygen tank is empty and reads “0” is it 0 gauge pressure or 0 atmospheric pressure*
0 gauge pressure
(if pressure was truly 0, it would be collapsed)
the cylinder actually contains O2 at atmospheric pressure or 14.7 psi or 1 bar
what are gas-cylinder pressures, art line pressures, ventilator pressures such as peak inspiratory pressures?
gauge pressures
what is the pneumonic for the gas laws
Prince Charles (pressure) had TB (boyle’s temp) and was given Vitamin G (Volume, Gay Lussac’s)
what is the law:
At a constant temperature, the volume of a given gas varies inversely with the absolute pressure.
boyle’s law of temperature
P1 x V1 = P2 x V2
what is the law:
At a constant pressure, the volume of a given gas varies directly with the absolute temperature.
charles’ law of pressure
V1 / T1= V2 /T2
example: helium balloons on a mailbox shrink in the cold; inflatable cuff of LMA expands in an autoclave
think VTICU. V comes before T
what is the law:
At a constant volume, the absolute pressure of a given mass of gas varies directly with the absolute temperature.
Gay Lussac’s Law of Volume
P1 / T1 = P2 /T2
think physical therapist. P comes before T
when squeezing an ambu bag, does the pressure go higher or lower
higher
is kelvin necessary in the gas laws*
YES
kelvin = celcius + 273
The lower the atmospheric pressure, the _____ the boiling point.
lower
pressure varies DIRECTLY with temp
what is the law:
In a mixture of gases, the pressure exerted by each gas is the same as that it would exert if it was alone in the container.
Partial pressure exerted by any single gas in a combination of gases is directly proportional to its % composition of the gas mixture.
dalton’s law of partial pressures
P1 + P2 + P3 = Ptotal
what is:
Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules (a mole).
avogadro’s hypothesis
what is avogadro’s number:
6.022 x 10 to the 23 power
number of atoms/molecules in 1 mole
what is the ideal gas law
PV = nRT
R is the universal gas constant
The gas laws combined with Avogadro’s hypothesis
At STP (standard temp and pressure), one mole of any gas occupies _____ liters
22.4 liters
what is STP
0 C, 760 mmHg, dry (no water vapor)
is nitrous (N2O) a liquid in a cylinder, except for the vapor at the top ?
yes
this is why the pressure gauge does not apply
TRUE OR FALSE
With an oxygen cylinder, as the pressure on the gauge decreases, so also does the amount of gas (moles which determines liters).
TRUE
what is the temperature above which no amount of pressure can liquefy a gas
critical temperature
what is the pressure to liquefy a gas at its critical temperature
critical pressure
what does solubility depend on (4 things)
-partial pressure of the gas
-temp
-gas
-liquid
what is the law:
At a certain temperature, the amount of a given gas dissolved in a given liquid is directly proportional to the partial pressure of the gas in equilibrium with the liquid
henry’s law
what is overpressurizing an example of?**
henry’s law
what is this known as?
increase concentration of isoflurane in the blood, the concentration or partial pressure of isoflurane should be increased. This is utilized at the induction of anesthesia when a higher concentration of the anesthetic than necessary for maintenance, or a loading dose, is delivered to speed uptake.
overpressurizing
what law is this an example of?
breathing air under pressure as scuba diver causes more nitrogen into solution in tissues
henry’s law
what is this?
A change in any of the factors in determining an equilibrium causes the system to adjust or reduce or counteract the effect of the change.
Le Chatelier’s principle
think about how when you put a pot to boil on the stove, right before it boils it has little air bubbles at the bottom (this is the gas escaping from the liquid)
what is this an example of?
If patient is cold at the end of an anesthetic, the inhaled anesthetic will be more soluble in the blood, causing the patient to wake up more slowly. (delayed emergence)
Le chatelier’s principle