Periodicity + Atomic Radii + Ionisation Energy and Electronegativity Flashcards

1
Q

What are four different characteristics that change going up and down a group or across a period?

A

1) Atomic Radius
2) Ionic Radius
3) Melting Point
4)Electrical conductivity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Which way is a period?

A

Across the table

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is atomic radius?

A

basically the radius of the atom. the distance from the inside nucleus and the outer electrons,

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

How does atomic radius change as you go down a group?

A

Atomic radius increases. The lowest elements have the longest atomic radii

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

How does ionic radius change as you go down a group?

A

Ionic radius increases. The lowest elements have the widest atomic radii

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why do atomic radius and ionic radius change as you go down a group?

A

Elements lower down have more electrons → More electrons need more shells to put them in → The more shells an element has, the wider it is → The longer the distance from the middle to the edge → a longer radius

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How does atomic radius change as you do across a period?

A

Atomic radius decreases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How does ionic radius change as you go across a period?

A

Ionic radius decreases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why do atomic radius and ionic radius change as you go across a period

A

elements further to the right have more protons → protons have a positive charge → more protons means more positive charge → more positive charge in the middle means more pulling in of the outside negative electrons towards the middle → so electrons are closer to the middle → the distance from the middle to the outside electrons is smaller → a smaller atomic radius
RADIUS ONLY INCREASES WHEN YOU ADD A NEW ELECTRON SHELL, NOT WHEN YOU ADD MORE ELECTRONS TO AN EXISTING SHELL

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What two characteristics have the same periodic trends?

A

Atomic Radius and Ionic Radius. Both increase in atomic radius as you go down a group and decrease in atomic radius as you move along a group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

How does atomic radius periodic change from neutral atoms to ions?

A

it doesn’t. the particle further right with more protons will have more pull and a smaller atomic radius. The particles further down with more electrons will have more shells and so a larger atomic radius

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What does isoelectronic mean?

A

two or more atoms or ions with the same number and arrangement of electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What process is necessary to melt a substance?

A

melting a substance requires adding enough energy to overcome the attractive forces holding the solid structure together

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What does a high melting point mean?

A

it means that the substance has strong attractive forces holding its particles together

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What kind of melting point do non-metals usually have?

A

non-metals generally have a lower melting point than metals because they are held together by a weaker London dispersion force

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What kind of melting point do metals usually have and why?

A

metals generally have a high melting point because they are held together by strong metallic bonds that take a lot of energy to break

16
Q

How does the melting point of metals correspond to their state at room temperature?

A

because metals typically have a high melting point, the vast majority of metals are solid at toom temperature because their melting point is higher than room temperature

17
Q

How does the melting point of non-metals correspond to their state at room temperature?

A

because non-metals typically have a low melting point, the vast majority of non-metals are gaseous at room temperature, because their melting point (and boiling points) are lower than room temperature

18
Q

What are some common metals?

A
  • iron
  • lead
  • aluminium
  • Silver
  • calcium
  • sodium
  • copper
  • mercury
  • gold
19
Q

WHy does the melting point change across a period?

A

elements further to the right have more free electrons in their valence shells → electrons are negatively charged particles → more negatively charged particles → more attraction → more strength to the metallic bonds that make up the metal substances → stronger attractive forces holding the substance together → harder to break the bonds in the substance → higher metling point

20
Q

How does melting point change across a period?

A

There are no real patterns. Metals held by strong metallic forces will GENERALLY have higher melting points that non-metals held together by weak London dispersion forces

21
Q

Why do giant covalent structures structures have a high melting point?has the highest melting points and why?

A

elements with a giant covalent structure are held together by many covalent bonds. Each atom of the element is covalently bonded to other atoms in their immediate vicinity. The number and strength of the bonds in the structure mean that it requires lots of energy to break apart the solid structure of the substance. An example is silicon.

22
Q

Which metal is an exception to the “solid at room temperature” trend?

A

mercury

23
Q

Which non-metal has a higher melting point than the metal sodium?

A

the non-metal sulfur has a higher melting point than the metal sodium

24
Q

What is electrical conductivity?

A

the ability of a substance to carry an electric current since electricity is the flow of electrons

25
Q

What should you consider when figuring out how conductive a substance is?

A

electrons to move?

26
Q

What is the electrical conductivity of metals?

A

metals have a high electrical conductivity

27
Q

Why do metals have a the level of electrical conductivity that they do?

A

metals are held together by metallic bonds → metallic bonds have delocalised electrons, that float freely among the atoms of the substance → more electron freedom → more flow of electricity → more flow of electricity means higher electrical conductivity

28
Q

What is the electrical conductivity of nonmetals?

A

Nonmetals tend to have low electrical conductivity

29
Q

Why do nonmetals have the electrical conductivity that they do?

A

nonmetals tend to form covalent bonds (some exist as monatomic atoms, basically lone and without any bonds) → electrons still move around, but they’re stuck in the space between atoms instead of moving around freely in the substance → less freedom of electrons → less flow of electricity → low electrical conductivity

30
Q

What are delocalised electrons?

A

electrons that float freely among the atoms of the substance

31
Q

What side of the periodic table are metals in?

A

the left and middle mostly, except for hydrogen

32
Q

What side of the periodic table are nonmetals in?

A

the right mostly + hydrog

33
Q
A

picometers

34
Q

Do semimetals behave like metals or nonmetals?

A

both. sometimes like metal and sometimes like nonmetals

35
Q

What kind of conductivity do semimetals have?

A

they have medium electrical conductivity

36
Q

How do you determine which element has a larger or smaller atomic radius if they are in the same period?

A

atomic radius decreases across a period → Basically the further you move right, the smaller the atomic radius is → The elements closest to the left will have the largest atomic radius + the elements closest to the right will have the smallest atomic radius

37
Q

What is periodicity?

A

trends and patterns found in the periodic table