Periodic Patterns Flashcards

1
Q

What is covalent radius

A

Half the distance between nuclei of atoms that are covalently bonded together

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2
Q

As you go down a group, covalent radius…

A

Increases

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3
Q

Why does covalent radius increase as you go down a group

A
  • number of electron shells increases
  • increased shielding
  • electrons further away from nucleus
  • atom size increases
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4
Q

As you go across a period, covalent radius…

A

Decreases

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5
Q

Why does covalent radius decrease as you go across a period

A
  • electrons are gradually filling up energy levels
  • more protons
  • increased nuclear charge
  • electrons pulled in closer and tighter
  • atom size decreases
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6
Q

What unit is atomic size measured in

A

Picometers (pm)

1 x 10^-12 m

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7
Q

What is Van der Waals radius

A

Half the distance between atoms nuclei that aren’t bonded together

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8
Q

What is the first ionisation energy

A

The energy required to remove 1 mole of electrons from 1 mole of gaseous atoms

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9
Q

What is the general equation for the first ionisation energy

A

M (g) ——> M+ (g) + e-

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10
Q

What is the second ionisation energy

A

The energy required to remove a second mole of electrons

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11
Q

What is the general equation for the second ionisation energy

A

M+ (g) ——> M 2+(g) + e-

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12
Q

What is the third ionisation energy

A

The energy required to remove a third mole of electrons

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13
Q

What is the general equation for the third ionisation energy

A

M 2+(g) ——> M 3+(g) + e-

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14
Q

As you go down a group, ionisation energy…

A

Decreases

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15
Q

Why does ionisation energy decrease as you go down a group

A
  • number of electron shells increases
  • atomic size increases
  • outer electrons are further away from nucleus
  • increased shielding
  • less energy required to remove e-
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16
Q

As you go across a period, ionisation energy…

A

Increases

17
Q

Why does ionisation energy increase as you go across a period

A
  • gradually filling up e- shells
  • more protons
  • nuclear charge increases
  • outer e- held tighter and closer to nucleus
  • atomic size decreases
  • more energy required to remove e-
18
Q

What is electronegativity

A

The measure of an atoms attraction for bonding electrons

19
Q

What does it mean if an atom is said to be highly electronegative

A

It has a strong attraction for bonding electrons

20
Q

As you go down a group, electronegativity…

A

Decreases

21
Q

Why does electronegativity decrease as you go down a group

A
  • number of e- shells increases
  • shielding increases
  • outer e- further away from nucleus
  • less attraction for bonding e-
22
Q

As you go across a period, electronegativity…

A

Increases

23
Q

Why does electronegativity increase as you go across a period

A
  • more protons
  • nuclear charge increases
  • covalent radius decreases
  • +ve nucleus attracts bonding electrons more strongly
24
Q

Why does group 8 (noble gases) not have electronegativity values

A

They have no bonding electrons

25
Q

What can electronegativities be used for

A

Predicting the type of bonding that would occur between atoms of 2 elements

26
Q

How are elements in the periodic table arranged

A

In order of increasing atomic number

27
Q

What are groups

A

Vertical columns within the table containing elements with similar chemical properties resulting from a common number of outer electrons

28
Q

What are periods

A

Rows of elements arranged with increasing atomic number, demonstrating an increasing number of outer electrons and a move from metallic to non-metallic characteristics

29
Q

Which elements form metallic bonds

A

Li, Be, Na, Mg, Al, K, Ca

30
Q

Which elements form covalent molecules

A

H2, N2, O2, F2, Cl2, P4, S8 and fullerenes (e.g. C60)

31
Q

Which elements form a covalent network

A

B, C (diamond and graphite), Si

32
Q

Which elements are monatomic

A

The noble gases