Controlling Rates Flashcards
Activated complex
The unstable arrangement of atoms formed at the maximum of the potential energy barrier
Why do chemists need to control the rate of reaction
To ensure processes are economical and safe
As reactants are used up during the process…
the rate will decrease, and the reaction slows down
Average rate
Change in quantity / change in time
gs^-1
Relative rate
1 / t
s^-1
Collision theory
For a chemical reaction to occur, the reactant molecules must collide with enough energy
What is activation energy (Ea)
The minimum kinetic energy required for a reaction to occur
Factors that control the rate which reactant molecules collide:
temperature concentration pressure particle size use of a catalyst
For exothermic reactions, ΔH will always be
Negative
For endothermic reactions, ΔH will always be
Positive
What is the effect of catalysts on activation energy
catalysts lower the activation energy