Pectins and Gums Flashcards

1
Q

What is dietary fiber?

A

Dietary fiber is the edible parts of plants or carbs that are resistant to digestion and absorption.

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2
Q

What are the important polysaccharides in foods?

A

Pectins and gums

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3
Q

Why are pectins and gums important polysaccharides in foods?

A

Pectins and gums are important because of their functional properties.

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4
Q

What are uses for pectins and gums?

A

Thickeners, stabilizers and gelling agents.

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5
Q

What are pectic substances?

A

Important constituents of plant tissue

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6
Q

What are different types of pectic substances?

A

Protopectin, pectinic acids, pectins and pectic acid.

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7
Q

What is considered as a linear polymer of D-galacturonic acid joined by α-1,4 glycosidic linkages?

A

Pectic substances

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8
Q

Each glycosidic linkage is a _________ bond.

A

Cross-planar

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9
Q

How are pectic substances classified?

A

Based on the number of methyl ester groups attached to the polymer.

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10
Q

Which derivative of pectic substances does not have a methyl group?

A

Pectic acid

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11
Q

Where is protopectin formed?

A

Protopectin forms in immature fruits

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12
Q

Where is pectinic acid formed?

A

Pectinic acid forms in ripened fruits

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13
Q

Where is pectic acid formed?

A

Over-ripe fruits

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14
Q

Which pectic substance forms a gel?

A

Pectinic Acid

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15
Q

Which pectic substnace is insoluble in water?

A

Protopectin

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16
Q

True or False. The degree of esterification varies for pectins.

A

True

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17
Q

What compound needs to be present for low-methoxyl pectins to form a gel?

A

Calcium

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18
Q

What needs to be added to high-methoxyl pectins for a gel to form?

A

Sugar and acid

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19
Q

What is commonly used to form pectin jellies?

A

High-methoxyl pectins

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20
Q

Why is pectin hydrophillic?

A

Due to the large number of polar hydroxyl groups and charged carboxyl groups

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21
Q

True or False. The positive charge on the pectin molecule, coupled with their attraction to water, keeps them apart, so they form a sol.

A

False. The negative charge does this.

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22
Q

How does pectin gel formation occur?

A

Decrease the forces that attract the pectin molecules for water or increase the forces that attract the pectin molecules to each other.

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23
Q

How does sugar help with gel formation?

A

Sugar competes with water, making water less available to bond with pectin molecules

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24
Q

How doe acid help with gel formatin?

A

Acid reduces the pH and the charge on the pectin molecules. Making the pectin molecules no longer repel each other.

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25
What are junction zones?
Attractive forces between molecules that help form the 3D network.
26
What is the purpose of junction zones?
To form pockets that trap water.
27
What was formed when the following occurs: 1) water binds to ionic polar groups on pectin 2) pectin molecules are negatively charged and hydrated 3) they do not react to each other
Pectin sol
28
What was formed when the following occurs: 1) Sugar is added 2) Acid is added
Pectin gel
29
What is something that decrease pectin interaction with water?
Sugar
30
What is something that increases pectin molecules interaction with each other?
Acid, water trapped in network and pectin interacting with junction zones
31
Pectin content of fruit depends on what factors?
The type of fruit and the maturity or ripeness
32
How ca you obtain low-methoxyl pectin?
By demthylating pectin with enzymes, acid or alkaline.
33
What is the critical control point of making jelly?
Boiling time
34
What is a gum?
A group of complex hydrophilic carbohydrates containing thousands of monosaccharides units?
35
What is the most common monosaccharide unit in a gum?
Galactose
36
True or false. Gums are also referred to as hydrocolloids.
True
37
What are characteristics of hydrocolloids?
Highly branched, cannot form gels, form stable aqueous colloidal dispersions or sols, and very viscous
38
True or false. Gum is an insoluble fiber.
False. Gum is a soluble fiber
39
What are 2 examples of seed gums?
Guar bean and locust bean gums?
40
What are seed gums?
Branched polymers containing only mannose and galactose
41
Which seed gum has a higher galactose ratio guar bean or locust bean?
Neither
42
Which seed gum has a higher mannose ratio guar bean or locust bean?
Locust
43
What seed gum stabilizes ice cream?
Guar bean
44
What seed gum is a stabilizer in dairy and processed meat products?
Locust bean
45
What are plant exudates?
Complex, highly branched polysaccharides
46
What are two examples of plant exudates?
Two examples of plant exudates would be gum arabic and gum tragacanth.
47
What plant exudate is highly soluble in water?
Gum arabic
48
What plant exudate forms very viscous sols?
Gum tragacanth
49
What is an application of gum arabic?
Stabilize emulsions and control ice crystallization
50
What is an application of gum tragacanth?
Stabilizer in salad dressings, ice ream and confections. To give a creamy texture to food.
51
How are microbial exudates produced?
Using fermentation by microorganisms
52
What is the most common microbial exudates?
Xanthan
53
What gum forms viscous sols that are stable over a wide pH and temperature?
Xanthan
54
True or false. Seaweed polysaccharides are able to form gels under certain conditions.
True
55
What is agar noted for?
Its strong, transparent, heat-reversible gels
56
Agar contains what?
Agarose and agaropectin
57
Agarose and agaropectin are polymers of what?
β-D- and α-L-galactose
58
Where can you obtain agar?
Red seaweed
59
Where can you obtain alginates?
Brown seaweed
60
Alginates form gel in the presence of what ions?
Calcium
61
True or False. Alginates contain mainly D-mannuronic acid and L-guluronic acid.
True
62
What are 2 forms of cellulose that intend to increase viscosity of foods?
CMC and MC
63
64
What is a sol?
A fluid colloidal system of two or more components
65
What is a gel?
A non fluid colloidal network or polymer network that is expanded throughout its whole volume by a fluid.
66
In sol formation what promotes gel?
Attraction! Specifically pectin molecules attraction
67
In sol formation what prevents gel formation?
Repulsion! Hydrophilic interactions and water hydration
68
In gel formation how do you decrease repulsion?
Adding sugar or acid
69
What factors affect pectin gel formation?
Degree of methylation, sugar content, pH, Calcium ion, endpoint temperature, boiling time
70
What is the salt form of alginic acid and gum mainly extracted from cell walls of brown algae?
Sodium alginate
71
True or false.Alginate-based hydrogel can be used for encapsulation and biomaterials.
True
72
Alkaline pH produces what color?
Violet-blue or turquoise