p block elements Flashcards
why does Ga have small size
Poor shielding of 3d e’s
In Boron family, at. radius order
B<Ga<Al<In<Tl
Order of IE in boron family
B>Tl>Ga>Al>In
Order of EN in boron family
B>Tl>In>Ga>Al
Boron
non metal, hard, high MP & BP, IE & EN, forms ionic but covalent cmpds
Lowest MP in boron family in
Ga
Boron family prop
Soft metals, high conductivity, low MP & BP
MP order in boron familiy
B>Al>Tl>In>Ga
BP in boron family
decreases down
density in boron family
increases down
+3 stability in boron family
Al>Ga>In>Tl
+1 stability in boron family
opp of +3
Tl +3 is a ____ agent
oxidising
IE in carbon family
C>Si>Ge>Pb>Sn
MP in carbon family
More than B family
C>Si>Ge>Pb>Sn
BP in carbon family
decreases down
density order in carbon family
Si<C<Ge<Sn<Pb
OS of Carbon
-4 to +4
-4 stability in carbon family
decreases down due to increases in size
+4 stability in carbon family
decreases down due to inert pair effect
+4 order in carbon family
Si>Ge>Sn>Pb
When size of X increases, stability with Si
decreases
Covalent char increase with
decrease in size
Ionic dihalides order
CX2<SiX2<GeX2<SnX2<PbX2
Sn 2+ is a _______
reducing agent
Order of tetrahalides
MF4>MCl4>MBr4>MI4
Why is PbI4 unknown?
Inert pair effect
Order of catenation
C»Si>Ge=Sn