OVERALL MIDTERM 2 Flashcards

1
Q

Nonpolar covalent bond

A

Electrons shared EQUALLY between atoms (no separation of charge)

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2
Q

Polar covalent bond

A

Electrons shared UNEQUALLY between atoms (separation of charge)

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3
Q

Electronegativity trend

A
  • Difference less than 0.4: Nonpolar
  • Difference between 0.4-2.0: Polar
  • Difference greater than 2.0: Ionic
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4
Q

Formal charge

A

Valence electrons - LP - Number of bonds

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5
Q

Nonbonding electrons

A

Valene electrons - 8(n)/2

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6
Q

Resonance bond rules

A
  • Single Bond: 3LP
  • Double bond: 2 LP
  • Triple bond: 1 LP
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7
Q

Base names alkanes

A
  • Methane
  • Ethane
  • Propane
  • Butane
  • Pentane
  • Hexane
  • Heptane
  • Octane
  • Nonane
  • Decane
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8
Q

Rules for naming alkanes (3)

A
  • Go with the lower substituent when naming
  • When 2 or more identical substituent present, use di try prefix
  • Substituent name should be alphabetical order
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9
Q

Alkane naming format

A

Substituent number - (substituent name)(base name)

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10
Q
  • Ane to -yl
A

When there’s one less than base

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11
Q

Electron group geometry

A

Count electron groups around central atom (LP and bonding atoms)

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12
Q

Electron group geometry shapes

A
  • Linear
  • Trigonal planar
  • Tetrahedral
  • Trigonal bipyramidal
  • Octahedral
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13
Q

Molecular shape

A

Only count atoms bonded to central atom and occurs when lone pairs present

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14
Q

Inphase

A

Overlap and form bond

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15
Q

Molecular shape shapes (BLT)

A
  • Bent
  • Linear
  • Trigonal pyramidal
  • T shape
  • Seesaw
  • Square planar
  • Square pyramidal
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16
Q

Outphase

A

Doesnt overlap and create a node

17
Q

Sigma bond

A

Overlap of orbitals head to head and single bonds

18
Q

Pi bond

A

Overlap of p orbitals side by side and multiple bonds

19
Q

Hybridizations

A
  • Sp: 2 electron groups
  • Sp2: 3 electron groups
  • Sp3: 4 electron grou[s
  • Sp3d: 5 electron groups
  • Sp3d2: 6 electron groups
20
Q

Constructive interference

A

Forms bonding molecular orbital

21
Q

Destructive interference

A

Forms anti bonding molecular orbital with node

22
Q

Bonding order

A

Bonded electrons - anti bonding electrons /2

23
Q

Bond order trend

A
  • BO 1: single bond
  • BO 2: Double bond
  • BO 3: Triple bond
  • BO 1/2: Single bond with 1 electron
24
Q

Paramagnetic

A

Contains unpaired electrons

25
Q

Diamagnetic

A

Contains paired electrons

26
Q

Units of k

A
  • Zero order: mol -1 L s-1
  • First order: s-1
  • Second order: L mol-1 s-1
27
Q

Number prefixes

A
  • Mono
  • Di
  • Tri
  • Tetra
  • Penta
  • Hexa
  • Hepta
  • Octa
  • Nona
  • Deca