FINAL - SECTION 5 Flashcards

1
Q

Reaction rate

A

Represented as [ ]/T and measures how fast concentration is (concentration and time)

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2
Q

+ sign

A

Product

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3
Q
  • sign
A

Reactant

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4
Q

What do you do with the mole quantity

A

Put it at the bottom of fraction in equation

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5
Q

Unit of reaction rate

A

M/S

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6
Q

Differential rate law

A

Measures rate and concentration

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7
Q

Rate law

A

k[A]^n

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8
Q

Zero order

A

Rate is constant and independant on concentration (k[A]^0)

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9
Q

First order

A

Rate is dependant on concentration ( k[A]^1) and 2x

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10
Q

Second order

A

Rate is dependant on concentration (k[A]^2) and 4x

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11
Q

Units of k

A
  • Zero order: M L s-1
  • First order: s-1
  • Second order: L M-1 s-1
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12
Q

Multiple rate reaction

A

Overall order becomes the sum of reactant exponents ( rate = k[A]^m[A]^n, overall order is m+n)

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13
Q

Integrated rate law

A

Concentration and time

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14
Q

What do we do with minutes in integrated rate law

A

Convert to seconds

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15
Q

“Plot of inverse”

A

Second order

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16
Q

What does [A]0 mean

A

Initial concentration

17
Q

Kinetic graph interpretation

A

Whichever graph is most linear is what the order is ([A] vs time, ln[A], or 1/[A])

18
Q

Half life

A

How long it takes for half the reactants to be consumed

19
Q

Collision theory

A

Reactants must collide to reactant (higher concentration = higher probability)

20
Q

Activation energy

A

Minimum energy needed for molecules to collide

21
Q

H+

A

Endothermic (absorb)

22
Q

H-

A

Exothermic (release)

23
Q

Transition state

A

Top of energy curve

24
Q

Arrhenius equation

A

Relate reaction and temperature

25
Q

Reaction mechanism

A

Sequence of elementary steps by which a chemical reaction occurs

26
Q

What happens to the moles in reaction mechanism

A

You can make it into a power (eg. 2NO + Cl = 2NOCl = k[NO]^2[Cl]

27
Q

Catalyst

A

Increase rate of reaction by decreasing activation energy

28
Q

Homogenous catalyst

A

Same phase as reactant

29
Q

Heterogenous catalyst

A

Different phase as reactant