ORGCHEM Flashcards

1
Q

The study of compounds that contain carbon.

A

Organic Chemistry

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2
Q

Are all carbon compounds organic?

A

False

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3
Q

Characteristics of sp3 (-ane)

A

Single bond, 4 sigma bond, 0 pi bond, Tetrahedral, 109.5°

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4
Q

Characteristics of sp2 (-ene)

A

Double bond, 3 sigma bond, 1 pi bond, Planar, 120°

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5
Q

Characteristics of sp (-yne)

A

Triple bond, 2 sigma bond, 2 pi bond, Linear, 180°

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6
Q

R - R structure

A

Alkane

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7
Q

R = R structure

A

Alkene

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8
Q

R ≡ R structure

A

Alkyne

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9
Q

R - OH structure

A

Alcohol

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10
Q

RC=OH structure

A

Aldehyde

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11
Q

RC=OR structure

A

Ketone

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12
Q

RC=OOH structure

A

Carboxylic acids

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13
Q

R - X structure

A

Alkyl halide

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14
Q

R - O - R structure

A

Ether

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15
Q

RC=OX structure

A

Acid halide

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16
Q

RC=OOR

A

Ester

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17
Q

RC=ONH2

A

Acid amide

18
Q

R - NH2

19
Q

No carbonyl group is found in _____.

20
Q

Which of the following is not an alipatic
hydrocarbon?
a. n-octane
b. propylene
c. n-tridecane
d. toluene

A

d. toluene

21
Q

Which of the following contains sp-hybridized
carbon?
a. C4H8
b. C3H6
c. C5H8
d. C6H12

22
Q

R = R + H2 —> R - R

A

Hydrogenation of Alkene

23
Q

R - X + Mg –> R - Mg - X

A

Hydrolysis of Grignard reagents

24
Q

2R - X + 2Na –> R - R + 2NaX

A

Wurtz Reaction

25
Addition of HX to ordinary alkenes, the hydrogen become attached to the carbon atom containing the most hydrogens, forming the more stable carbonium ion.
Markovnikov’s Rule
26
If the addition of hydrogen bromide to alkenes is carried out in the presence of organic peroxides.
Anti-Markovnikov’s Rule
27
Organic compounds that has similar physical and chemical properties with benzene
Aromatic Hydrocarbons
28
Part of a molecule where most of its chemical reactions occur
Functional Group
29
Which of the following molecules is unsaturated? a. C3H8 b. C5H10 c. CH3OH d. CH4
b. C5H10
30
**REMEMBER** **Alkane & Alcohol** - Saturated Hydrocarbon **Alkene & Alkyne** - Unsaturated Hydrocarbon
OK
31
When ethyl bromide is treated with sodium in dry ether, the product is a. propane b. methylpropane c. butane d. ethane
c. butane
32
Alkenes are commonly prepared via elimination reaction, which of the following is NOT an elimination reaction? a. Dehydration of alcohol b. Dehalogenation of vicinal dihalide c. Dehydrohalogenation of alkyl halide d. Hydrogenation of alkynes
d. Hydrogenation of alkynes
33
Hydrogenation of alkenes in the presence of a poisoned palladium catalyst produces a. alkane b. alkyl halide c. alkyne d. alcohol
a. alkane
34
When 2-butyne undergoes ozonolysis, the main product is _______. a. carbon dioxide b. acetaldehyde c. acetic acid d. acetone
c. acetic acid
35
How many isomers does xylene have? a. 1 b. 2 c. 3 d. 4
c. 3
36
Which of the following straight-chain alkanes can be conveniently prepared by Wurtz reaction? a. heptadecane b. nonane c. icosane d. none of the above
c. icosane
37
Friedel-Crafts acylation of benzene with acetyl chloride in AlCl3 yields a. chlorobenzene b. cumene c. acetophenone d. benzaldehyde
c. acetophenone
38
Vinylbenzene is also known as _______ a. styrene b. cumene c. mesitylene d. durene
a. styrene
39
Hydrocarbon derivatives used as a main ingredient in automobile antifreeze a. ethylene glycol b. isopropyl alcohol c. propylene d. toluene
a. ethylene glycol
40
Reaction of alcohol and a carboxylic acid is known as ________ a. saponification b. nuetralization c. esterification d. epoxidation
c. esterification
41
No carbonyl group is found in a. aldehyde b. ketone c. ester d. epoxide
d. epoxide (epoxide is ether)
42
Carboxylic acids are reduced by lithium aluminum hydride to the corresponding _________. a. primary alcohols b. secondary alcohols c. tertiary alcohols d. All of these
a. primary alcohols