Organic Chemistry SL Flashcards

1
Q

Hydrocarbon

A

Compound containing only carbon and hydrogen

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2
Q

Empirical Formula

A

Simplest whole number ratio of the elements present in a compound

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3
Q

Molecular Formula

A

Total Number of atoms in each element, present in a molecule of the compound. A molecular Formula is an integer multiple of the empirical formula

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4
Q

Homologous Series

A

Series of compounds that have the same functional group, and each member differs from the next by a common structural unit.

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5
Q

Functional Group

A

Atom or Group of Atoms in a molecule that gives it its characteristics chemical properties, this is the reactive part of a molecule

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6
Q

Aromatic Compounds

A

Have a benzene ring

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7
Q

Alkane functional group name

A

Alkyl

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8
Q

Alkene functional group name

A

Alkenyl C = C

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9
Q

Alcohol functional group name

A

Hydroxyl - oh

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10
Q

Ether Functional Group name

A

Ether c- o - c

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11
Q

Aldehyde Functional Group name

A

Carbonyl - Refer to book

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12
Q

Ketone Functional Group name

A

Carbonyl

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13
Q

Carboxylic Acid Functional Group name

A

Carbonxyl

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14
Q

Halgenoalkane Functional Group name

A

Halo (Chloro , bromo etc)

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15
Q

Amine Functional Group name

A

Amine - NH2, NHR, NR2

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16
Q

Ester functional Group name

A

Ester , refer to book

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17
Q

Nitrile functional group name

A

Nitrile, refer to book

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18
Q

Amide functional group name

A

Carboxamide

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19
Q

Why does Amines have different functional Groups

A

Amines are classified as primary, secondary, or tertiary.

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20
Q

Compounds without benzene ring are

A

Aliphatic

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21
Q

What’s the functional group in aromatic compounds

A

Benzene ring

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22
Q

Boiling Point of Homologous Series

A

As number of carbons in a homologous series increases, the boiling point increases. This is due to the the London forces between molecules increasing as the relative molecular mass increases.

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23
Q

Why is the boiling point of alcohols larger that alkanes

A

Due to hydrogen bonding between alcohol molecules

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24
Q

Solubility of Alcohol trend

A

As the length of the hydrocarbon chain increases, solubility decreases. (Alcohol soluble only in water)
This is due to the long hydrocarbon chain preventing water molecules on either side from hydrogen bonding to one another.

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25
Saturated Compounds
Compounds that do not contain multiple bonds aka double carbon or more bonds.
26
Unsaturated Compounds
Example Benzene, compounds containing carbon carbon double bonds or carbon carbon triple bonds.
27
Rule in naming Ethers
Short chain is the alkoxy Longer chain is the alkane Alkoxy alkane
28
Rule in naming esters
Named after their carboxylic acid they are derived from
29
Ester formed by
Reaction between carboxylic acid and an alcohol
30
Primary Amines functional group
NH2
31
Secondary Amine functional Group
NHR
32
Teritiary Amine functional Group
NR2
33
Simplest forms of isomerism are
Structural isomerism
34
Structural Isomers
Two or more compounds that have the same molecular formula but different structural formula
35
Isomers with different functional groups are
Functional group isomers
36
Original Benzene structure
Kekule Benzene, alternating single an double bonds between carbon atoms
37
New benzene structure
Contains a ring of 6 delocalised electrons, That is formed due to the p orbitals having a side on overlap to form a pie delocalised system.
38
Evidence for benzene structure
Carbon Carbon Bond lengths Thermochemical Evidence Number of isomers Reactions
39
Benzene structure evidence via carbon carbon bond length
All C - C bond length in benzene is the same, and are intermediate in length between a c - c an c = c bond.
40
Bond Lengths determined by
X ray crystallography
41
Thermochemical Evidence of benzene
????
42
Evidence from the number of isomers in benzene structure
Looking at the number of isomers in a halogenobenzene shows only 3 isomers, however following kekules rule their should be 4 isomers.
43
Reaction of benzene
Benzene does not exact like Alkenes and does not undergo addition reactions under normal conditions and does not decolonize bromine water. But it undergoes substation reaction.
44
Alkane Reactions
Combustion, substitution,
45
Why are alkanes generally unreactive
High strengths of C- C and C - H bonds make them unfavourable to break, C - C and C - H are non polar and thus are unlikely to attract polar ions or molecules.
46
Alkanes react with Halgones
In the presence of sunlight or UV, alkanes react with Halogens (Write Equation down) This process is called substitution.
47
Steps of Free Radical Substitution
Initiation Propagation Termination
48
What’s Free Radicals
Species with an unpaired electron, and are thus very reactive due to the presence of an unpaired electron
49
Homolytic Fission
Occurs during initiation, Homolytic fission is breaking a covalent bond in such a way that each atom takes an electron from the bond to form two radicals.
50
Propagation is an example of a
Chain Reaction
51
Write down the equation of ethane and bromine
Page 450 TB
52
Why are Alkenes more reactive
It contains a double bond that represents a region of high electron density and is thus able to attract electrophiles. The second component of a pie bond of c=c is weaker than a normal c- c sigma bond and is thus easily broken
53
Electrophile
Reagent that is attracted to regions of high electron density and accepts a pair of electrons to form a covalent bond.
54
Alkenes/ Alkynes reactions
Addition, and addition polymerisation
55
Alkenes and halogen
RTP
56
Alkenes and Hydrogen
Heated in the presence of a catalyst, ex nickel to form alkane. Process called hydrogenation
57
Alkenes and hydrogen Halides
Alkenes react with halides ex HI, HCL by bubbling alkene through concentrated solution of the hydrogen halide at 100 degrees celcius. Forms halogenoalkane
58
Why is HI and Alkene a rapid reaction whereas HCl and Alkenes a slow reaction
Since HI has weaker bonds, it needs less energy and thus the reaction is faster compared to HCl that was stronger bonds. H and Cl is more electronegative than H and I
59
Alkenes and Water
Passing alkene through concentrated sulfuric acid at rtp and then warming the product with water Forms alcohol Needs heat and sulfuic acid
60
Distinguishing between alkanes and Alkenes
Alkenes, bromine water - orange to colorless Alkane - Bromine water - no colour change
61
What’s catalytic hydration
Alkene and water with sulfuric acid
62
How is polyethene formed
High temp, high prefer in presence of small amount of oxygen/ hydrogen peroxide