Organic Chemistry Qs Flashcards
CH3CHOHCH3
Propanol
CH3COCH3
Propanone
CH3COCH3–>CH3COCHOHCH3
Identify bonds broken and formed
Broken C to O
Formed OH +CH
A= propene B=propanol C=propanone Boiling points are -48, 56 and 82 Identify boiling points
Propene= -48 van see waals forces
Propanol= 82 hydrogen bonds
Propanone=dipole dipole forces
Benzene
3 double bonds has two pi electors
Electrons in benzene ring are delocalised
All carbon carbon bonds in benzene are if same length
Free radical substitution-ethane
Explain how the occupancy if another hydrocarbon in product provides evidence
Traces of butane
Explain why propanone has a lower boiling point than butane
Fewer electrons
Fewer intermolecular forces between bonds
Isomers pairs
Propan1ol and propan2ol
Aldehydes and ketones
Account for greater reactivity of alkenes compared to alkanes
Presence of double bond
Electron rich
Describing bonding in benzene
6 signs bonds
From c-H formed from 6 P orbitals
Type of reaction in relux
Saponification
Two features of an elimination reaction
-H2O
Change to unsaturated
Benzene
All carbon to carbon bonds in benzene are identical
Bonds intermediate between single and double
Give two reasons alcohols have higher boiling point that corresponding alkane
Higher MR
Hydrogen bonds of H-O