Organic Chemistry (Intro) Flashcards
Lewis acid
Electron pair acceptor (Electrophile)
Lewis base
Electron pair donor (Nucleophile)
Free radical
Highly reactive, electrically neutral atoms or groups of atoms with an unpaired electron
Homolytic Fission
Covalent bond breaks such that the shared pair of electrons are split equally between the two bonded atoms (forms free radicals)
Heterolytic Fission
Covalent bond breaks such that shared pair of electrons are split unequally between two bonded atoms. One atom takes both electrons to form an anion
Constitutional Isomerism
Same molecular formula, different structural formula
Stereoisomerism
Same molecular formula and structural formula, different spatial arrangement of atoms
Enantiomerism
Molecule has no plane of symmetry, a chiral centre, and a non-superimposable mirror image