Organic Chemistry Fuels Flashcards

1
Q

Sources of fuels

A
  1. Petroleum (crude oil)

2. Natural gas

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2
Q

Petroleum (crude oil)

A

A naturally occurring mixture of hydrocarbons (mainly alkanes)

Thick, black liquid

Non-renewable resource (limited)

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3
Q

Natural gas

A

A mixture of many gases, mainly made up of methane and other short-chain alkanes such as ethane, propane and butane

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4
Q

Hydrocarbons

A

Compounds made up of only carbon and hydrogen

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5
Q

Complete combustion

A

Complete combustion occurs when there is sufficient oxygen present

Complete combustion of hydrocarbons produces carbon dioxide, water and a lot of heat

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6
Q

Incomplete combustion

A

Incomplete combustion occurs when there is insufficient oxygen present

Carbon monoxide and soot obtained

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7
Q

Fractions

A
Lighter fractions —> smaller hydrocarbons 
Heavier fractions —> bigger hydrocarbons 
Petroleum gas
Petrol (gasoline)
Naphtha 
Kerosine (paraffin)
Diesel oil
Lubricating oil
Bitumen
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8
Q

Petroleum gas

A
USES
Fuel for cooking and heating
APPROXIMATE BOILING POINT RANGE
Below room temperature
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE
1-4
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9
Q

Petrol (gasoline)

A
USES
Fuel for motorcars
APPROXIMATE BOILING POINT RANGE
35-75
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE 
5-10
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10
Q

Naphtha

A

USES
Feedstock for making petrochemicals such as plastics and detergents
APPROXIMATE BOILING POINT RANGE
70-170
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE
8-12

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11
Q

Kerosine (paraffin)

A

USES
Fuel for aircraft engines, cooking using oil stoves and heating
APPROXIMATE BOILING POINT RANGE
170-250
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE
10-16

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12
Q

Diesel oil

A

USES
Fuel for diesel engines in trains, buses and lorries
APPROXIMATE BOILING POINT RANGE
250-340
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE
15-25

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13
Q

Lubricating oil

A

USES
For lubricating machines;for making waxes and polishes
APPROXIMATE BOILING POINT RANGE
350-500
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE
19-35

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14
Q

Bitumen

A
USES
For making road surfaces and roofing
APPROXIMATE BOILING POINT RANGE
Over 580
APPROXIMATE NUMBER OF CARBON ATOMS PER MOLECULE 
More than 70
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15
Q

Is each fraction pure?

A

No. Each fraction consists of hydrocarbons with similar range of carbon atoms per molecule

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16
Q

Relationship

A

Boiling point increases

Number of carbon atoms per molecule increases

17
Q

Fractional distillation of petroleum in an oil refinery

A
  1. Petroleum is heated into a vapour in the furnace
  2. The vapour is passed into the fractionating column
  3. The hot vapour cools and condenses as it rises up the column
  4. Lighter fractions with lower boiling points are collected at the top of the column as gases
  5. Heavier fractions with higher boiling points are collected at the bottom of the column as residue
18
Q

Environmental issues of combustion of fuels

A
  1. Greenhouse effect

2. Air pollution