Organic Chemistry Alkanes Flashcards
Organic compounds
Contains carbon and one or more other elements such as hydrogen, chlorine, oxygen or nitrogen
Homologous series
A family of organic compounds with the same general formula and similar chemical properties
Alkanes, Alkenes, Alcohols, Carboxylic acids
They gradually change their physical properties as the number of carbon atoms per molecule increases
Functional group
An atom or group of atoms that gives a molecule it’s characteristic properties
Formulas of organic compounds
- Empirical formula
- Molecular formula
- Structural formula
Empirical formula
The simplest formula of a compound
Molecular formula
Indicates the actual numbers of each kind of atom in a molecule of a substance
Structural formula
Indicates how the atoms are bonded to each other within the molecule of a substance
Bonds
Carbon 4 bonds
Hydrogen 1 bond
Oxygen 2 bonds
Alkanes
A homologous series of hydrocarbons that contains only carbon-carbon single covalent bonds
Saturated
No functional groups
CnH2n+2
Physical properties of alkanes
- Low melting and boiling points
- Insoluble in water
- Soluble in organic solvents
As it goes down the series: - Melting and boiling point increases
- Becomes more viscous (density increases)
- Becomes less flammable
Why does the melting and boiling points of alkanes increases going down the series
The melting and boiling points of alkanes increases as their molecular sizes increase. This is because as the sizes of the alkane molecules increase, the forces of attraction between the molecules also increase
Why does alkanes become more viscous as it goes down the series
Alkanes will become more viscous as their molecular sizes increase. This is due to the stronger forces of attraction between the alkane molecules
Why does alkanes become less flammable going down the series
As the sizes of the alkane molecules increase, the percentage of carbon in the alkane molecules also increase
Chemical properties of alkanes
- Combustion
2. Substitution reaction
Combustion
Exothermic reaction
alkane + oxygen —> carbon dioxide + water