ORGANIC CHEMISTRY Flashcards

1
Q

WHAT IS a hydrocarbon

A

a compound that only contains hydrogen and carbon atoms

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2
Q

what is an alkane

A

they are saturated hydrocarbons

and they have carbon carbon single bonds

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3
Q

what are the first four alkanes

A

methane
ethane
propane
butane

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4
Q

what is the general formula for alkanes

A

CnH2n+2

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5
Q

what happens if you change the length of a carbon chain

A

the properties of the hydrocarbon change

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6
Q

properties of short hydrocarbons

A

less viscous
more volatile (lower boiling point)
more flammable

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7
Q

what are the products of the complete combustion of any hydrocarbon

A

carbon dioxide and water

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8
Q

what can hydrocarbons be used as

A

they can be used as fuels because of the energy that they release when they combust completely

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9
Q

complete combustion equation

A

hydrocarbon + oxygen ——- carbon dioxide + water

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10
Q

what is crude oil

A

it is fossil fuel and contains a mixture of hydrocarbons

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11
Q

how are the different compounds in crude oil seperated

A

fractional distillation

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12
Q

how does fractional distillation work

A

the oil is heated until most of it has turned into a gas, the gases then enter a fractionating column
in the column theres a temperature gradient
the longer hydrocarbons have high boiling points, they condense back into liquids and drain out of the column early on, when theyre near the bottom
the shorter hydrocarbons have lower boiling points they condense and drain near the top of the column where its cooler
the crude oil mixture is now separated into different fractions

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13
Q

importance of crude oil

A

oil provides the fuel for most modern transport
the petrochemical industry uses some of the hydrocarbons from crude oil as feedstock to make new compounds for use in things like polymers solvents lubricants and detergents

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14
Q

what is cracking

A

splitting up long chain hydrocarbons

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15
Q

why would we crack longer chain hydrocarbons

A

longer chain hydrocarbons form thick gloopy liquids which aren’t useful and short hydrocarbons are more useful as they are more flammable, so they make good fuels and are in high demand

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16
Q

why is cracking useful

A

longer hydrocarbon molecules produced from fractional distillation are turned into smaller more useful ones by cracking

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17
Q

what type of reaction is cracking

A

thermal decomposition reaction

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18
Q

process of catalytic cracking

A

the first step is too heat long chain hydrocarbons to vaporise them
then the vapour is passed over a hot powdered aluminium oxide catalyst
the long chain molecules split apart on the surface of the specks of catalysts

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19
Q

whats another way of cracking hydrocarbons other than catalytic cracking and how does it work

A

steam cracking

if you vaporise them mix them with steam and then heat them to a very high temperature

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20
Q

What are alkenes

A

they are unsaturated hydrocarbons

and they have double carbon carbon bonds

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21
Q

what are the first 4 alkenes and how many c’s does it have

A

ethene (2cs)
propene (3cs)
butene (4cs)
pentene (5cs)

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22
Q

what is the general formula for alkenes

A

CnH2n

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23
Q

in a large amount of oxygen, alkenes…..

A

combust completely to produce only water and carbon dioxide

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24
Q

why is it hard for alkenes to combust completely what happens when this happens

A

there isn’t enough oxygen in the air for this, so when you burn them they tend to undergo incomplete combustion

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25
what happens in incomplete combustion
carbon dioxide and water are still produced but carbon monoxide and carbon is also produced
26
what is the equation for incomplete combustion
alkene + oxygen ------- carbon + carbon monoxide + carbon dioxide + water
27
what is a functional group
is a group of atoms in a molecule that determine how that molecule reacts
28
why are alkenes a homologous series
because they all have the same functional group and react in similar ways
29
what is the addition of hydrogen called
hydrogenation
30
what happens when alkenes react with hydrogen
its in the presence of a catalyst | opens up the double bond to form a single bond
31
what happens when alkenes react with steam
its passed over a catalyst | water is added across the double bond and an alcohol is formed
32
how can ethanol be made
mixing ethene with steam and then passing it over a catalyst
33
what happens when alkenes react with halogens
the c=c carbons become bonded to a halogen atom | becomes a single bond also
34
how do you test for alkenes
add bromine water to the compound if its an alkene the bromine water will turn colourless
35
what colour is bromine water
orange
36
what happens if you add bromine water to an alkane
the bromine water will stay orange as there are no alkenes
37
what are plastics made up of
they are made up of long chain molecules called polymers
38
what are polymers
they are long molecules formed by many monomers
39
what are addition polymers made from
unsaturated monomers
40
how to draw the displayed formula for an addition polymer
start by drawing the two alkene carbons and then replace the double bond with a single bond and extra bond to each of the carbons fill in what you need to drawing lines above the carons draw brackets and then put an n next to it
41
what functional group do alcohols have and what do they end in
-oh and end in ol
42
what is the general formula for alcohols
CnH2n+1OH
43
what are the first 4 alcohols
methanol ethanol propanol butanol
44
what do all alcohols have in common
they have the functional group oh-
45
what similar properties do the first four alcohols have
they are flammable and they undergo complete combustion in air to produce carbon dioxide and water theyre all soluble in water and have a neutral ph they react with sodium they can be oxidised by reacting with oxygen to produce a carboxylic acid
46
what can the first four alcohols be used as
fuels
47
what can alcohols be used as in industry
solvents
48
when does complete combustion occur
when theres oxygen
49
another way that ethanol can be made other than the use of ethene
by fermentation
50
how does fermentation work
fermentation uses an enzyme in yeast to convert sugars into ethanol carbon dioxide is also produced
51
what is the word equation for fermentatoin
yeast | sugar ------- ethanol + carbon dioxide
52
when does fermentation happen fastest
when at 37 degrees in a slightly acidic solution under anaerobic conditions
53
what functional group do carboxylic acids have
-COOH
54
what are the first four carboxylic acids
methanoic acid ethanoic acid propanoic acid butanoic acid
55
how are carboxylic acids drawn
eg CH3COOH CH3 DRAWN NORMALLY then another single bond to c the c double bond to o drawn diagonally upwards then single bond downwards diagonally OH
56
how do carboxylic acids react with carbonates
they react to produce a salt, water and carbon dioxide
57
what do the salts formed end in, when in the reaction of an carboxylic acid and a carbonate eg ethanoic
-anoate | ethanoate
58
ethanoic acid + sodium carbonate -----
sodium ethanoate + water + carbon dioxide
59
what happens when carboxylic acids dissolve in water
they ionise and release h+ ions
60
what functional group do esters have
-COO-
61
how are esters formed
from an alcohol and a carboxylic acid
62
what catalyst is usually used when forming an ester
an acid catalyst
63
what is the word equation for the formation of an ester
acid catalyst | alcohol + carboxylic acid ---------------------- ester + water
64
ethanoic acid + ethanol =
(acid catalyst) ethyl ethanoate + water
65
how to draw esters
take out the OH from the carboxylic acid and take out the H from the start of the alcohol join the acid and alcohol together with a bond down with the c and the o separately add the h20 on the side
66
how many types of monomers in additional polymerisation
only one type containing a c=c bond
67
no of products in addition polymerisation
only one product formed
68
functional groups involved in addition polymerisation
carbon carbon double bond in monomer
69
how many types of monomers in condensation polymerisation
two monomer types each containing two of the same functional groups or one monomer type with two different functional groups
70
how many products formed in condensation polymerisation
two types of product- the polymer and a small molecule
71
functional groups involved in condensation polymerisation
two reactive groups on each monomer
72
what functional groups do amino acids contain
a basic amino group NH2 and an acidic carboxyl group (COOH)
73
what polymers can amino acids form
polypeptides via condensation polymerisation
74
what are sugars
are small molecules that contain carbon, oxygen, and hydrogen
75
what small molecule is lost when two amino acids react together to form a new bond
water
76
amino acids can bond together by condensation polymerisation state the type of polymer formed from this reaction
polypeptides
77
give three examples of naturally occurring polymers
proteins starch DNA