Organic Chemistry 2 Flashcards
What determines how hydrocarbons react
Functional group (e.g double c bond in alkenes)
Functional group determines…
How hydrocarbons react
Functional group of alkene
Double c bond
All members of the same homologous series have the same…
Functional group
Which type of combustion do alkenes undergo
Incomplete
Alkenes burn in air with a…flame
Smoky
Alkenes…in air with a smoky flame
Burn
Process of alkene reacting with hydrogen is called..
Hydrogenation
2 Conditions needed for hydrogenation (alkene reacting with hydrogen)
150 degrees Celsius
Nickel Catalyst
A hydrogenation reaction (alkene reacting with hydrogen) needs a temperature of…and a…catalyst
150 degrees Celsius
Nickel catalyst
Hydrogenation is where an alkene reacts with….at 150 degrees Celsius and the presence of a nickel catalyst
Hydrogen
Hydrogenation (alkene reacting with hydrogen) forms an…
Alkane
Process of alkene reacting with water (steam) is called…
Hydration
Alkene reacting with water (steam) forms..
Alcohol
Hydration is where…reacts with…to form…
Alkene
Water (steam)
Alcohol
Hydration vs hydrogenation
Hydration: water (steam) reacts with alkene to form alcohol
Hydrogenation: hydrogen reacts with Alkene to form alkane
3 conditions needed for hydration (water (steam) reacting with alkene) are… and …
300 degrees
70 atm (pressure)
Catalyst- phosphoric acid
Alkene reacting with water (hydration) forms an alcohol and needs a temperature of…and pressure of..and ….catalyst
300 degrees
70atm
Phosphoric acid
Alkenes react quite…with halogens
Rapidly
3 uses of alcohols are alcoholic drinks…and …
Fuels
Solvents
Alcohol functional group
OH
2 ways to produce ethanol
Hydration: ethene (alkene) + water (steam) forms ethanol (alcohol)
Fermentation: yeast added to glucose solution produces ethanol solution and carbon dioxide
Name for process where glucose produces ethanol and carbon dioxide
Fermentation
3 conditions needed for fermentation
Yeast (added to glucose solution)
Warm (30 degrees)
Sealed container (anaerobic)
1 advantage of hydration method to obtain ethanol
High yield
2 advantages of fermentation method to obtain ethanol
Low temperature (little energy required)
Glucose comes from plants so comes from renewable resource
2 disadvantages of hydration method to obtain alcohol
High temperature so lots of high energy required
Alkene comes from crude oil which is a non renewable resource
1 disadvantage of fermentation method to obtain ethanol
Ethanol product is in aqueous solution so requires energy to be purified by distillation
Alcohols are…in water
Soluble
Alcohols form…solutions
Neutral
As the number of carbon atoms in alcohols increases its…decreases
Solubility (becomes less soluble in water)
As the number of…in alcohols increases it becomes less soluble in water
Carbon atoms
What can be observed during reaction of alcohol with sodium
Bubbles
As hydrogen gas is given off
Alcohol reacts with sodium to form…and…
Sodium meth/eth/prop/but oxide
Hydrogen
One key example of oxidising agent (e.g when alcohols react with oxidising agent)
Acidified potassium dichromate
Acidified potassium dichromate is a good example of a..
Oxidising agent
Acidified…is a key example of an oxidising agent
Potassium Dichromate
Alcohols react with oxidising agents to form…and water
Carboxylic acid
Functional group of Carboxylic acid
COOH
In water, Carboxylic acids are…acids
Weak
In…Carboxylic acids are weak acids
Water
Carboxylic acids react with alcohols to form..and…
Esters
Water
Must know this name! Ethanoic acid react with ethanol to form the ester…
Ethyl ethanoate
True or false, the reaction between ethanoic acid and ethanol to form an ester (ethyl ehanoate) + water is reversible
True
Amino acids have…different functional groups
2
2 different functional groups for amino acids are… and..
Amine group
Carboxylic acid group
Polypeptide meaning
Polymer made from only one type of amino acid
Name for polymer made up of different types of amino acid
Protein
Name for polymer made up of only one type of amino acid
Polypeptide
Protein vs polypeptide
Polypeptide is a polymer made up of only one type of amino acid
Protein is a polymer made up of different types of amino acid
Why can amino acids take part in condensation polymerisation
They have 2 different functional groups (amine group and Carboxylic acid group)
DNA consists of 2 chains made from monomers called
Nucleotides
Starch and cellulose are polymers of…
Glucose
Glucose makes up the polymer…and …
Starch
Cellulose
Both…and…are polymers of glucose (but the glucose is arranged in slightly different ways)
Starch
Cellulose
Crude oil is a …resource (non renewable)
Finite
Crude oil contains a mixture of molecules called…
Hydrocarbons
A hydrocarbon is a… made up of only …and…atoms
Molecule
Carbon
Hydrogen
(This is the hydrocarbon definition)
Are Alkanes saturated or unsaturated molecules
Saturated
(Alkenes are unsaturated)
As hydrocarbon molecules get bigger they become…viscous
More
As hydrocarbon molecules get bigger they become…viscous
More
High viscosity carbons mean they flow…
Very Slowly
Flammability tells us how easily a hydrocarbon…
Combusts (burn)
The bigger the hydrocarbon molecule gets, the…flammable it is
Less
The bigger the hydrocarbon molecule gets, the….it’s boiling point
Higher
Methane/ ethane/ propane/ butane are all…at room temperature because they have boiling points lower than room temperature
Gases
Hydrocarbon fuels release…when burned
Energy
Combustion is another word for…
Burned
During combustion of hydrocarbon why are the hydrogen and carbon atoms oxidised
They react with oxygen
What are fractions
What the crude oil is separated into during fractional distillation- in each fraction the hydrocarbons have a similar number of carbon atoms to each other
Is the fractionating column hotter at the top or bottom
Hot at bottom
Cool at top
Fractions contain hydrocarbons with a similar number of…
Carbon atoms
Feedstock meaning
Chemical used to make other chemicals
True or false, cracking of alkanes can produce both alkanes and Alkenes
True
Catalytic cracking uses high…and a catalyst
Temperature
Steam cracking uses high…and steam
Temperature
Which is more reactive out of alkanes and Alkenes
Alkenes
To test for Alkenes we use orange bromine water and shake the Alkene with bromine water. If Alkenes are present the bromine water turns..
Colourless
Alcohols react with sodium to form…..oxide + hydrogen
Meth/eth/prop/but