organic chemistry Flashcards

1
Q

what is a hydrocarbon

A

molecules that consist of only hydrogen and carbon

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2
Q

differ between saturated and unsaturated

A

SATURATED: single bonded, alkanes
UNSATURATED: double or triple bonded, forms kink, alkenes/alkynes

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3
Q

chemical formulas

A

ALKANE: CnH2n+2
ALKENE/CYCLOALKANE: CnH2n
ALKYNE: CnH2n-2
BENZENE: C6H6

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4
Q

whats a alkyl group

A

branches attached to the main structure

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5
Q

properties of alkanes

A

non polar
only LD present
as increase in size IMF increase
1-4 gas
5-40 liquid
40+ waxy solid

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6
Q

what is a structural isomer

A

when 2 molecules have the same molecular formula bur different arrangements of atoms

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7
Q

describe reactions of alkanes

A

stable and unreactive
can undergo combustion or substitution reactions

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8
Q

what is alkyl halide

A

when a alkane undergoes a susbstition reaction called halogenation and a H atom is replaced with a halogen

often polar with DD

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9
Q

what is a aliphatic hydrocarbon

A

structures are based on straight or branched chains or rings of carbon atoms

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10
Q

what is a stereoisomer

A

same number of atoms, with DB in same position but different 3D geometry around it

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11
Q

differ between cis and trans

A

cis- the two groups are on the same side of DB
trans- the two groups are on opposite sides of DB

can not be changed by simple rotation, bonds must be broken and reformed

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12
Q

what is function group with a example

A

group of atoms within a molecule that determine its properties

multiple bonds, make more reactive

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13
Q

traits of aromatic hydrocarbons

A

unsaturated, chemically stable
equal bond lenghts
non polar
insoluble in water
between alkanes and alkenes in reactivity

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14
Q

when will benzene not be the parent chain

A

carbons chains with 6+
double or triple bonds
it will become a phenyl group

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15
Q

what are hydrocarbon derivatives

A

organic compounds based on hydrocarbons with addition of specific functional group

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16
Q

what does a alcohol have

A

a hydroxyl group C-OH

17
Q

differ between primary, secondary, and tertiary alcohols

A

1 OH bonded to terminal C
2 OH bonded to C with 2 alkyl groups
3 ‘’’’’’’’’ 3 alkyl groups

18
Q

what is it called when a benzene has 1 hydroxyl

how do you name it when 2+ HYDROXYL ARE BONDED TO a benzene

A

phenol

benzene is root word

19
Q

what is a ether

A

oxygen bonded betweenn 2 carbons
suffix oxy
short root- oxy - long group

20
Q

what is a thiol

A

contain sulhydryl group SH
ADD thiol

21
Q

what’s the difference between a ketone and aldehyde

A

the location of the carbonyl group

22
Q

what is a aldehyde

A

carbonyl group on C1
al, dial if 2
if attached to ring, carbaldehyde
bonded to a H

23
Q

What is a ketone

A

carbonyl group on lowest possible C, C2
one, dione or trione
may need to indicate postion
in cyclic the carbonyl is C1 and not in name

24
Q

what happens if a ketone and aldehyde are in the same structure

A

ketone=oxo
4-oxopentanal

25
Q

what is a carboxyl acid

A

carbon atom DB to one oxygen and single bonded to hydroxyl
oic acid
when on ring structure carboxyilic acid

26
Q

what is a ester

A

C DB to a O and SB to a second O
oate
name alkyl groupn attached to single bonded O
NAME REST

27
Q

what is esterfication

A

how esters are formed, a reaction between an acid and alcohol

28
Q

what are fats and oils

A

triglycerides made from long chaoins of fatty acids
fats are solid at room temp
oils are liquid at room temp

29
Q

what is a triglyceride

A

three acids bonded to an alcohol

30
Q

what is saponification

A

the soap making reaction, involves reacting a fat or oil with a strong base. breaks down the triglyveride into glycerin and soap

31
Q

what are polymers

A

chainlike molecules made by linking up smaller repeating chemical units

32
Q

differ between monomer and polymer

A

polymer- chainlike molecule made up by repeating smaller chemical units
monomer- the smaller repeating chemical units in a polymer

33
Q

differ between homo and copolymer

A

homo- polymer made up by a single type of monomer
co- two or more types of monomers combined to form chain

34
Q

differ between alkyl group and substituent group

A

alkyl- branch of carbons off the main structure of molecule, type of substituent
substituent- atom or group that replaces hydrogen in a organic molecule

35
Q

what is minimal amount of carbons to form a structural isomer

A

4- if you have less then four the carbons will always be in the same arrangement, making no possible isomers

36
Q

how does the addition of soap to water allow water to dissolve non polar molecules like oil

A

when soap is added to water the hydrophilic part of the soap interacts with the polar water molecules, while the hydrophobic part interacts with non polar oil molecules. the hydrophilic tail surrounds the oil and the hydrophilic heads contact the water, thus allowing water
to dissolve oil.