chemical equilibrium Flashcards

1
Q

chemical equilibrium

A

a state at which rates of forwards reactions and reverse reactions are equal and the concentrations of the reactants and products remain constant

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2
Q

why is equilibrium dynamic

A

the rate at which reactants become products and vice versa remains constant, and this activity is continuous

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3
Q

3 things necessary to establish equilibrium

A

reversible reaction
closed environment
constant temp

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4
Q

equilibrium constant

A

Keq
not all products will be converted ro reactants, vice versa
products/ reactants
Keq>1 favours forwards
Keq<1 favours reverse
favoured means higher # of moles and concentration
solids or liquids are given value of 1

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5
Q

how do you find Keq for reverse reaction

A

take reciprocal of forwards reaction
ex. Keqf = 280
Keqr = 1/280

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6
Q

what is le Chateliers Principle

A

states that if system at equilibrium is subjected to an external stress, the equilibrium will shift to minimize the effect of that stress

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7
Q

what are external stresses that will cause a shift

A

concentration
pressure
temperature

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8
Q

what is a catalyst

A

speeds up both forwards and reverse reactions, helps reach equilibrium sooner

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9
Q

Endothermic and exothermic

A

endo= heat on reactant side +H
increase temp shift right
decrease temp shift left

exo=heat on product side -H
increase temp shift left
decrease temp shift right

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10
Q

change in pressure

A

increase in pressure shift towards side with fewest moles
decrease in pressure shift towards side with most moles

=moles no change

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11
Q

what change in temp favours endo or exo reactions

A

endo increase reaction in temp
exo reaction decrease in temp

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12
Q
A
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