organic chemistry Flashcards
hydrocarbon
any compound formed between hydrogen and carbon only
alkanes
saturated compounds (single carbon bonds)
methane
-one carbon atom with hydrogen bonds
-ch4 formula
ethane
-two carbon atoms bonding with 3 hydrogen atoms each
-CH6 formula
propane
-three carbon bonds with 8 hydrogen atoms
-CH8 formula
butane
4 carbon atoms with 10 hydrogen atoms
CH10 formula
homolgous series
similar properties reacting in a diffrent way
isomers
molecules that have the same molecular formula but different structural formula
alkane proterties
-boiling point increases with chain length
-gas to liquid to solid further down chain
-longer alkanes are more viscious
-shorter alkanes are more flammable
viscious
thick and sticky
complete combustion
-hydrocarbon + oxygen > carbon dioxide +water
-for fuel (exothermic reaction)
crude oil
-made of of diffrent hydrocarbons
crude oil can be seperated into fractions,
fractions
-simpler, more useful hydrocarbons of diffrent lengths
fractional distillation
-fractions of crude oil can be separated by fractional distillation
-oil is heated until it turns into a gas, gasses enter fractioning column
how does fractional distillation work
longer hydrocarbons have higher boiling points . when they reach boiling point, they condense back into a liquid and drain near the bottom
shorter hydrocarbons condense later due to their lower boiling points
List the fractions from lowest to highest boiling point
Refinery gases- domestic heating and cooking
Petrol- fuel for cars
kerosene- fuel for aircraft
diesel oil- fuel for ships
bitumen- surface of roads
cracking
-form of thermal decomposition
-turns long saturated alkanes into smaller saturated alkanes and an alkene
what does cracking involve
heat, and a catalyst
vaporised hydrocarbons are passed over a powdered catalyst.
longer chained molecules are split apart on the surface of a catalyst
name a catalyst used for cracking
aluminium oxide
what is incomplete combustion
not enough oxygen for complete combustion
products of incomplete combustion
carbon monoxide and soot
dangers of carbon monoxide
-carbon monoxide binds with haemoglobin in red blood cells, and reduces the amount of blood flowing around the body
-lack of oxygen in blood supply can lead to a coma or death
dangers of soot
tiny particles of carbon are released into atmosphere and when falls, soot can cause poor air quality and respiratory problems
alkenes
hydrocarbons that fit the general formula CnH2n
except they have one C–C double bond in their carbon chain
ethene
c2H4
propene
C3H6
butene
C4H8
Pentene
C5H10
alkenes reaction with bromine
alkenes react with bromine by breaking the C–C and adding the bromine atoms in
C2H4+ Br2> C2H4Br2
addition reaction(adding bromine atoms into alkene)
reaction happens without uv light- alkenes more reactive than alkanes
works with bromine water (orange)
turns orange to colourless
addition polymer
molecules with a C–C double bond add into chains
small molecules add together are called monomers
long chain they form are called polymers
common polymers
polyethene- drinks bottles shopping bags
propene- storage boxes, climbing ropes
chloroethene- wire insulation, drainspipes