Organic Chemistry Flashcards

1
Q

What is crude oil?

A

A mixture of different length hydrocarbons

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2
Q

What are hydro carbons?

A

Compounds made up of carbon and hydrogen only

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3
Q

What is the simplest homologous series called?

A

Alkanes

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4
Q

What type of bonds do alkanes have?

A

They have single bonds between all carbon atoms (saturated)

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5
Q

What are characteristics of a homologous series?

A

Similar chemical properties, trends in physical properties, same general formula. All carbon atoms contain 4 bonds.

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6
Q

What is the general formula of an alkane?

A

CnH2n+2

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7
Q

Formula for methane

A

CH4

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8
Q

Formula for ethane?

A

C2H6

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9
Q

Formula for Propane?

A

C3H8

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10
Q

What is the formula for Butane

A

C4H10

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11
Q

What is the formula for Pentane?

A

C5H12

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12
Q

What does the molecular formula do?

A

Shows the number of atoms of each element present in the compound

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13
Q

What does structural formula do?

A

Shows the arrangement of atoms in a molecule in simplified form

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14
Q

What do display formulas do?

A

Shows every atom and every bond present in the molecule

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15
Q

What does empirical formula do?

A

Shows the simplest ratio of the atoms of each element present in a compound

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16
Q

As the number of carbon atoms increase, what do we see?

A

Boiling point increases
Stronger attractive forces between molecules
More energy required to overcome forces
Less volatile as chain length increases
become more viscous
Darker in colour
Burn less easily

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17
Q

What are structural isomers?

A

Compounds with the same molecular formula - but different structures and they must have the same number of each atom

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18
Q

What is substitution?

A

One atom is swapped with another atom

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19
Q

What condition is needed for substitution?

A

UV light

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20
Q

What is combustion?

A

A reaction where the hydrocarbon is burned in oxygen to release energy when used as fuel

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21
Q

what does complete combustion always produce?

A

Carbon dioxide and water

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22
Q

Where does a short chain hydrocarbon condense in a fractional distillation column?

A

The top sections

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23
Q

A hydrocarbon chain catches fire very easily. Does it have a short or long chain?

24
Q

As chain length increases, what happens to its viscosity?

A

It increases

25
As chain length decreases, what happens to its boiling point?
It decreases
26
What causes incomplete combustion?
Lack of oxygen
27
Products of incomplete combustion?
Carbon monoxide and water
28
What is fractional distillation used for in organic chemistry?
Separating gases
29
Why are different alkenes separated in fractional distillation?
Heat (different boiling points)
30
What must happen to the crude oil before fractional distillation?
They must be heated until hydrocarbons vaporise
31
What are alkenes?
Alkenes are hydrocarbons made from cracking alkanes
32
What kind of bond do alkenes have?
Double bond between 2 carbon atoms (unsaturated)
33
What is the general formula for Alkenes?
CnH2n
34
What are alkenes used to make?
Polymers
35
Are alkanes or alkenes more reactive?
Alkenes
36
What is the test for alkenes?
Add bromine water Alkene = orange to colourless Alkane = stays orange
37
What does cracking do?
Produces a smaller alkane and a smaller alkene
38
Is there a greater supply of longer or shorter chain hydrocarbons?
Longer
39
What chain has more demand in fuels?
Short chain
40
What is there a big demand for alkenes to make?
Polymers
41
What is significant about atoms when cracking a hydrocarbon?
No atoms are lost (allows us to write balance symbol equations)
42
How is cracking achieved?
Large hydrocarbons broken down by heating over a hot catalyst
43
What are polymers?
Large molecules made of 100s of repeating small molecules called monomers
44
What are alkanes used as?
Monomers
45
What are polymers used to make?
Plastics
46
How do we make polymers?
Process called addition polymerisation
47
What are 2 changes that occur during polymerisation?
1 Bond in double bonds break, many monomers join to make one long chain.
48
Why is the disposal of plastics (polymers) difficult?
They’re unreactive (non bio degradable) and cannot be broken down by bacteria - last 1000s of years!
49
What are advantages of burning plastics? (Polymers)
Saves up space and a source of energy
50
What are the disadvantages of burning plastics (polymers)
Release greenhouse gases Releases toxic gases Expensive to build a maintain the plant
51
What are the advantages of landfills?
No greenhouse gases Cheapest option
52
What are the disadvantages of landfills?
Uses large area of land Remains for 1000s of years
53
What are the different fractions in a fractional distillation column from hottest to coldest?
Bitumen, heavy fuel oil, diesel, kerosene, petrol, liquefied petroleum gases
54
What temperature does cracking occur?
600 degrees
55
Why is cracking necessary?
Smaller fractions are in more demand than large ones
56
What chemical is used for cracking?
Aluminium oxide