Organic Chemistry Flashcards
what kind of resource is crude oil
finite
where is crude oil found
rocks
what is crude oil a mixture of
a large number of compounds of different hydrocarbons
what is crude oil made of
remains of ancient biomass consisting mainly of plankton that was buried in mud
what is a hydrocarbon
a compound made of hydrogen and carbon only
what are alkanes
hydrocarbons
what is the functional group of alkanes
single bonds C-C
are alkanes saturated
yes
what do alkanes names end in
ane
general formula for alkanes
C. H
n. 2n+2
what name represents 1 carbon
meth
name for 2 carbons
eth
name for 3 carbons
prop
name for 4 carbons
but
name for 5 carbons
pent
name for 6 carbons
hex
name for 7 carbons
hept
name for 8 carbons
oct
name for 9 carbons
non
name for 10 carbons
dec
what are alkenes made of
hydrocarbon
functional group of alkenes
one carbon to double carbon bond
are alkenes saturated
no
what do alkene names end in
ene
general formula for alkenes
C. H
n. 2n
what kind of reaction is cracking
chemical
steps of cracking
- long hydrocarbon heated to vaporise and passed over a catalyst or mixed with steam.
- long hydrocarbon breaks down into a shorter alkane and an alkene.
- shorter alkene has a higher boiling point so condenses into a liquid
- the alkene has a lower boiling point so is collected as a gas
what is the catalyst in cracking
broken pot
how do you test for alkanes and alkenes in cracking
bromine water (orange liquid)
observation in bromine water if alkane present
no effect - stays orange
observation in bromine water if alkene is present
decolourises bromine water and changes colour from orange to colourless
why do alkenes turn bromine water colourless
more reactive due to double bond
what kind of process is fractional distillation
not a chemical reaction
why are some of the products made from cracking useful as fuels
they have shorter chains than the alkanes you started with so they are more flammable therefore a better fuel
what is fractional distillation used for
separating crude oils to make more useful substances that we use as fuels
which fuels are made from crude oil that we use
petrol, diesel fuel, kerosene, heavy fuel oil, liquified petroleum gases
what is bitumen/residue from fractional distillation used for
makes road surfaces
what is diesel fuel from fractional distillation used for
vans/ lorries
what is kerosine from fractional distillation used for
planes
what is petrol from fractional distillation used for
cars
what is fuel gas from fractional distillation used for
camping gas
what is the boiling point of short chain hydrocarbons
low
what is the boiling point of long chain hydrocarbons
high
what is the volatility of short chain hydrocarbons
high
what is the viscosity of short chain hydrocarbons
low
what is the flammability of short chain hydrocarbons
high
what is the volatility of long chain hydrocarbons
low
what is the viscosity of long chain hydrocarbons
high
what is the flammability of long chain hydrocarbons
low
what is viscosity
how easily something flows (more viscous =thick, less viscous = runny)
what are hydrocarbons burnt to be used as
fuel
what is the equation for burning hydrocarbons
hydrocarbon —-> carbon dioxide + water
what is combustion
when a fuels reacts with oxygen
what kind of reaction is combustion
oxidation
what is the process of complete combustion
a fuel burns with unlimited oxygen
makes carbon dioxide and water
energy is released
what does carbon dioxide cause
global warming
testing for complete combustion
set up a fuel
direct gases into equipment using a funnel
connect funnel to a tube (inside a beaker with ice and water )with cobalt chloride which turns blue with water
in this tube water vapour condenses into water
connect to another tube with limewater which turns cloudy if co2 is present
different types of pollution
carbon dioxide
water
carbon monoxide
carbon (particulates)
sulfur dioxide
nitrogen oxides
how is carbon dioxide made
complete combustion
how is water made
complete and incomplete
how is carbon monoxide made
incomplete
how is carbon (particulates) made
incomplete
how is sulfur dioxide made
fuels contain sulfur and react with oxygen
how are nitrogen oxides made
nitrogen and oxygen from the air react due to high temperatures
what does carbon dioxide cause
global warming
what does water pollution cause
nothing
consequence of carbon monoxide
poisonous to humans
consequence of carbon particulates
global dimming
consequence of sulfur dioxide
acid rain/ asthma
consequence of nitrogen oxides
acid rain/ asthma
oxygen in incomplete combustion
a fuel burns with limited oxygen
what does incomplete combustion make
carbon particulates
carbon monoxide
water
what is released during incomplete combustion
energy - exothermic but less than complete
why are alkenes unsaturated
they contain two fewer hydrogen atoms than the alkane with the same number of carbon atoms
what are functional groups responsible for
the reactions of organic compounds
what are plastics made up of
huge molecules (polymers)
that are made of lots of small molecules joint together (monomers)
what are monomers
small molecules with a double bond
what happens in addition polymerisation
monomers join together to create polymers
how do monomers join together
double bond breaks down to form a single c-c bond
these bond together to form a long chain
how do you name polymers
put poly in front of the monomer and the monomer in brackets
what is the use of poly(ethene)
plastic bags
what is the use of poly(propene)
rope/carpets
use of poly(styrene)
cups
use of poly(vinyl acetate)
glue
use of poly(vinyl chlorate)
doors/ windows
how do alkenes react with oxygen
burn with a smokier yellow flame compared to alkanes
what kind of combustion occurs when alkenes react with oxygen
incomplete combustion
how much energy is released when alkenes react with oxygen
less energy per mole in combustion than alkanes
why do alkenes have hydrogen added to them
they are unsaturated and more hydrogen can make them saturated
what kind of reaction is alkenes with hydrogen
hydrogenation reaction
how us hydrogen added to alkenes
add a hydrogen molecule across the double c=c bond
what conditions are needed for alkenes to react with hydrogen
60 degrees
nickel catalyst
what does adding hydrogen do to the molecules in alkenes
straightens the molecules
increases their melting point
because the strength of intermolecular forces is increased
how do you add a halogen to an alkene
add a halogen across the double c=c bond
how do you name the product of alkenes and halogens
di Halogen beginning, alkene name
what is produced when alkenes react with water (steam)
alcohol
how do you name an alcohol
number of carbons - ol
what conditions are needed for alkenes and water to react
high temperature
concentrated phosphoric acid as a catalyst
what happens to H2 in an alkene when hydrogen water or halogens are added
split into 2 Hs
what happens to H20 when hydrogen water or halogens are added to an alkene
split into a H and an OH
what happens to Br2 if hydrogen water or halogens react with alkenes
splits into 2 Brs
same for cl2 or I2
what are the uses of alcohols
cleaning
solvent
drinking
perfume
sanitising
antiseptic
fuel
start a fire
what is the functional group of alcohols
OH
what do the names of alcohols end in
ol
how do you draw an alcohol
draw the alkane and remove one hydrogen and add an OH group
how do you work out the structural formula of an alcohol with it drawn
break it into sections
what is ethanol used in
everyday practices
what are the two ways ethanol is produced industrially
fermentation
hydration of ethene
process of fermentation
extract sugar (glucose from crops)
add yeast to glucose (enzymes from yeast act as a catalyst)
conditions for fermentation
30 to 40 degrees
what is released in fermentation
co2
what kind of process is fermentation
batch process (stop and start)
advantages of fermentation
sugar found in plants - renewable
batch process - cheap equipment needed
more carbon neutral
disadvantages of fermentation
very slow
impure - needs fractional distillation so uses time and money
batch process means high labour cost
uses land which could be used to grow food
process of hydration of ethene
extract crude oil from the ground
oil refinery - fractional distillation then cracking to get ethene
hydration (add steam)
what is the catalyst in hydration of ethene
phosphoric acid
conditions needed for hydration of ethene
high temperature ans pressure
what kind of process is hydration of ethene
continuous
advantages of hydration of ethene
fast reaction
pure product]
95% yield
continuous so cheaper manpower
disadvantages of hydration of ethene
high tech equipment needed so expensive initially
high energy costs for high pressure
ethene is non renewable
how do alcohols react in the air
burn nbevause they are flammable
what happens when alcohols burn
they produce co2 and water
what happens when alcohols react with water
soluble in water so create a neutral solution
as number of carbon atoms increase as they get less soluble
what happens when alcohols react with sodium
create a sodium (alcohol) oxide and hydrogen
what happens when alcohols react with an oxidising agent
carboxylic acid and water
what is the functional group of carboxylic acids
COOH
what kind of acids are carboxylic acids
weak
how do carboxylic acids react
same way as acids used in the lab and have the same properties
Ph of carboxylic acids
4-6 (yellow or orange)
how do carboxylic acids react with water
produce acidic solutions
how do carboxylic acids react with metal carbonates
produce a salt , water and carbon dioxide which turns limewater cloudy
how do carboxylic acids react with alkalis
neutralisation (exothermic)
how do carboxylic acids react with metals
create salt and hydrogen
how do carboxylic acids and bases react
make salt and water
what makes carboxylic acids weak acids
do not ionise completely in solutions so don’t release many H+ ions
what does carboxylic acids begin weak mean
they have a higher pH than solutions of strong acids of the same concentrations
what do carboxylic acids reacting with alcohols form
esters
what is needed for alcohols and carboxylic acids to react
an acid catalyst
functional group of esters
COO
name of ester created by ethanoic acid and ethanol
ethylethanoate
formula of ethylethanoate
CH3COOCH2CH3
what is an important condensation polymer made on a large scale
polyester
what are condensation polymers made from
monomers
what are monomers not
alkenes
process of condensation polymerisation
monomers with two functional groups
when reacting they join together and lose a small molecule such as water
simple polymers are produced from two different monomers with two of the same functional groups on each monomer
what does one alcohol monomer have to be in condensation polymerisation
a diol (two oh group , one at each end)
what does one carboxylic acid have to be in condensation polymerisation
a dicarboxylic acid (two cooh groups, one at each end)
what do amino acids have
two different functional groups in a molecule
which functional groups do amino acids have
amine group and a carboxylic acid group
how are polypeptides produced
amine group and carboxylic acid group react by condensation polymerisation
how are proteins produced
different amino acids combined in the same chain
basic amino group formula
NH2
acidic carboxyl group formula
COOH
what is protein used in the human body for
haemoglobin in red blood cells to transport oxygen
antibodies in immune system
enzymes -catalysts
what does DNA stand for
deoxyribonucleic acid
what does the order of amino acids control
proteins properties and shapes
what kind of structure does DNA have
double helix structure
what is DNA made up of
two polymer chains of monomers called nucleotides
what are other naturally occuring polymers important for life
proteins (monomer is amino acids)
starch (monomer is glucose)
cellulose (monomer is glucose)
what are nucleotides
four different monomers