Organic Chemistry Flashcards

1
Q

Methyl Polar Protic

A

Sn2

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2
Q

Primary Polar Protic

A

Sn2

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3
Q

Secondary Polar Protic

A

Sn1/E1

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4
Q

Tertiary Polar Protic

A

Sn1/E1

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5
Q

Methyl Polar Aprotic

A

Sn2

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6
Q

Primary Polar Aprotic

A

Sn2

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7
Q

Secondary Polar Aprotic

A

Sn2

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8
Q

Tertiary Polar Aprotic

A

Sn1/E1

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9
Q

Methyl Strong Small Base

A

Sn2

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10
Q

Primary Strong Small Base

A

Sn2

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11
Q

Secondary Strong Small Base

A

E2

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12
Q

Tertiary Strong Small Base

A

E2

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13
Q

Methyl Strong Bulky Base

A

Sn2

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14
Q

Primary Strong Bulky Base

A

E2

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15
Q

Secondary Strong Bulky Base

A

E2

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16
Q

Tertiary Strong Bulky Base

A

E2

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17
Q

Polar Protic Solvents

A

Acetic Acid, H2O, ROH, NH3

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18
Q

Polar Aprotic Solvents

A

DMF, DMSO, Acetone, Ethyl Acetate

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19
Q

PCC

A

Oxidizes 1° alcohols to aldehydes
Oxidizes 2° alcohols to keytones

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20
Q

KMnO4

A

Oxidizes 1° alcohols to carboxylic acids
Oxidizes 2° alcohols to keytones

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21
Q

H2Cr2O4

A

Oxidizes 1° alcohols to carboxylic acids
Oxidizes 2° alcohols to keytones

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22
Q

NaBH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols

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23
Q

LiAlH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols
Reduces carboxylic acids to 1° alcohols
Reduces esters to 2° alcohols

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24
Q

LiAlH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols
Reduces carboxylic acids to 1° alcohols
Reduces esters to 2° alcohols

25
Q

N-H IR Peak

A

Sharp 3300

26
Q

O-H IR Peak

A

Broad 300-3300

27
Q

Triple Bond CO/CN

A

Medium 1900-2200

28
Q

CO Double Bond IR

A

Sharp 1750

29
Q

CC Double Bond

A

Weak 1600-1680

30
Q

Formyl Group

31
Q

Formaldehyde

32
Q

Formic Acid

33
Q

Acetyl group

34
Q

Acetaldehyde

35
Q

Acetic Acid

36
Q

Acetone

37
Q

Acetylacetone

38
Q

Acetophenone

39
Q

Benzyl Group

40
Q

Benzaldehyde

41
Q

Benzoic Acid

42
Q

Benzoin

43
Q

Styrene

44
Q

Acryl Group

45
Q

Acrolein

46
Q

Acrylic Acid

47
Q

Carboxyl Group

48
Q

Carboxylate Ion

49
Q

Carbonate Ion

50
Q

Carbonic Acid

51
Q

Cation-Exchange Chromatography

A

Has negative charged beads and attracts cations.

52
Q

Affinity Chromatography

A

Uses a bound receptor or ligand and an eluent with free ligand or a receptor for the protein of interest.

Histidine Tags are a good example.

53
Q

Pyrrole

54
Q

Short Chain Fatty Acids

55
Q

Amide

56
Q

Amine

57
Q

Imine

58
Q

Enamine