General Chemistry Flashcards

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1
Q

Boyle’s Law

A

P1V1 = P2V2

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2
Q

Charle’s Law

A

V1/T1 = V2/T2

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3
Q

Gay-Lussac’s Law

A

P1/T1=P2/T2

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4
Q

Hund’s Rule

A

e- only double up in orbitals if all orbitals first have 1 e-.

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5
Q

Aufbau Principle

A

Direction of increasing n+1 value.

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6
Q

Q < Keq

A

∆G < 0, reaction proceeds towards products –>

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7
Q

Q = Keq

A

∆G = 0, equilibrium

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8
Q

Q > Keq

A

∆G > 0, reaction proceeds toward the reactants <–

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9
Q

↓pH

A

↑respiration to blow off CO2

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10
Q

↓pH

A

↑respiration to blow off CO2

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11
Q

↑pH

A

↓respiration, trapping CO2

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12
Q

+∆H and +∆S

A

Spontaneous at HIGH temperatures.

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13
Q

+∆H and -∆S

A

Non-spontaneous at ALL temperatures.

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14
Q

-∆H and +∆S

A

Spontaneous at ALL temperatures.

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15
Q

-∆H and -∆S

A

Spontaneous at LOW temperatures.

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16
Q

Keq > 1

A

Favors product formation. ∆G < 0

17
Q

Keq = 1

A

Reaction is at equilibrium. ∆G = 0

18
Q

Keq < 1

A

Favors reactant formation. ∆G > 0

19
Q

1 atm to mmHg

A

1 atm = 760 mmHg

20
Q

1 atm to torr

A

1 atm = 760 torr

21
Q

1 atm to kPa

A

1 atm = 101.3 kPa

22
Q

1 atm to psi

A

1 atm = 14.7 psi

23
Q

How does the volume of a real gas compare to that of an ideal gas at moderately ↑P, ↓V or ↓T?

A

Real gases will occupy less volume than predicted by the ideal gas law because the particles have intermolecular attractions.

24
Q

How does the volume of a real gas compare to that of an ideal gas at extremely ↑P, ↓V or ↓T?

A

Real gases will occupy more volume than predicted by the ideal gas law because the particles occupy physical space.

25
Q

[H+]

A

[H+] = 10^-pH

26
Q

Are galvanic cells spontaneous?

A

Yes. ∆G < 0. +Ecell > 0. Anode = negative. Cathode = positive.

27
Q

Are electrolytic cells spontaneous?

A

No. ∆G > 0. -Ecell < 0. Anode = positive. Cathode = negative.

28
Q

Reduction Potential

A

Quantifies the tendency for a species to gain e- and be reduced. More positive Ered = greater tendency to be reduced.