organic chemistry Flashcards

1
Q

what are free radicals?

A

species with unpaired electrons

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2
Q

are the properties of a free radical

A

highly reactive

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3
Q

at breaks down the covalent bond betwwen Br2

A

ultraviolet

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4
Q

why is ultraviolet used in a free radical reaction

A

so that the Br has a lone pair of electrons
and becomes a free radical

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5
Q

what is the chemical properties of alkanes

A

unreactive
difference in electronegativity is low

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6
Q

name the order of the haloalkenes

A

chloro bromo
ioda floro

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7
Q

what are structural isomers

A

same molecular formula
different structural formula

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8
Q

what are sterioisomers

A

molecules with the same structural formula
atoms are arragened differently

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9
Q

what are nucleophilies

A

they have lone pairs which are attracted to the electron deficient carbon atom

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10
Q

what does the nucleophile do

A

donates lone pair of electrons to form a covalent bond

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11
Q

what are electron deficent elements

A

partial/positive charge

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12
Q

what are E isomers

A

trans isomers
the priority are on opposite planes of carbon

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13
Q

what are Z isomers

A

cis isomers
priority is on the same plane

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14
Q

what conditions is needed during a nucleophilic substitiution

A

the nucleophile should be in an aqueous solution
addition of ethanol to make it soluble

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15
Q

outline the steps of a nucleophilic substitution

A

lone pair–> to C atom—>
middle of bond
then nucleophile is replaced with halogen

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16
Q

what happens during nucleophillic elimination

A

lone pair–> H (forms a covalent bond)
H—> double carbon bond
C–> to halogen