Orbitals and Quantum Numbers Flashcards

1
Q

Erwin Schrödinger derived…

A

a complex mathematical formula to incorporate the wave and particle characteristics of electrons.
- Described with the wave function ψ

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2
Q

Electron density

A

The probability of finding an electron in a certain area of space is proportional to ψ2 and is called

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3
Q

The Schrödinger equation specifies

A

possible energy states an electron can occupy

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4
Q

The energy states are characterized by a set of

A

Quantum Numbers

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5
Q

Quantum numbers

A

describe the distribution of electron density in an atom

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6
Q

three quantum numbers describe

A

an atomic orbital

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7
Q

n

A

Principal quantum number - specifies size

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8
Q

l

A

Angular moment quantum number - specifies shape

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9
Q

ml

A

Magnetic quantum number - specifies orientation

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10
Q

Larger values of n correspond to…

A

larger orbitals

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11
Q

Shell

A

Orbitals with the same value of n

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12
Q

s orbitals

A

spherical in shape but differ in size
- 1s < 2s < 3s

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13
Q

p orbitals

A

hourglass shape

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14
Q

d orbitals

A

two hourglass shape or ring

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15
Q

f orbitals

A

christmas lights

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16
Q

ms

A

Electron spin quantum number - specifies an electron’s spin
- allowed values are +1/2 or -1/2

17
Q

Pauli exclusion principle

A

no two electrons can have the same four quantum numbers

18
Q

The energies of orbitals in the hydrogen atom depend only…

A

on the principal quantum number

19
Q

Electron configuration

A

describes how the electrons are distributed in the atomic orbitals

20
Q

Aufbau principle

A

electrons are added to the lowest energy orbitals first before moving to higher energy orbitals

21
Q

Hund’s rule

A

the most stable arrangement of electrons is the one in which the number of electrons with the same spin is maximized