O1: Intro to Organic Chemistry Flashcards

1
Q

What are the prefixes of hydrocarbons based on numbers of carbons?

A

1- Meth
2- Eth
3- Prop
4- But
5- Pent
6- Hex

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2
Q

What is a molecular formula?

A

The number of atoms

e.g C3H8

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3
Q

What is a structural formula?

A

The molecular formula broken down into structure

e.g CH3 CH2 CH2 CH3

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4
Q

What is a displayed formula?

A

A drawing showing covalent bonds

e.g. H. H
H-C- -C-H
H. H

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5
Q

What is a skeletal formula?

A

The shorthand of a displayed formula using lines

e.g. /\/\/\

a carbon at each point

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6
Q

Define what a functional group is

A

Specific groups of atoms or bonds within a molecule that are responsive for the chemical reactions of the molecule.

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7
Q

What are the names of branches on carbon chains?

A

1- Methyl
2- Ethyl
3- Propyl
4- Butyl
5- Pentyl

Act as a prefix to the name
e.g methylpropane

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8
Q

How does the number of what carbon the branch is in effect the name?

A

The carbon number that the branch is in comes before the name, but has to be the lowest number it can be.

e.g. 2-methylpentane
on the 2nd carbon

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9
Q

What is the empirical formula?

A

The simplest ratios of atoms in the molecule

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10
Q

What is an isomer?

A

Same molecular formula but the atoms are in different arrangements

-Structural
-Sterioisomer

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11
Q

What is structural isomerism?

A

Have the same molecular formula, but different structural formula

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12
Q

What is positional isomerism?

A

The functional group is attached to the main carbon chain in different locations

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13
Q

What is chain isomerism?

A

The carbon chains are arranged differently, so different carbon skeletons (maybe branched)

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14
Q

What is functional group isomerism?

A

The atoms are reorganised to give a different functional group

e.g alkene&raquo_space; cyclic alkane

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15
Q

What is sterioisomerism?

A

2 or more compounds have the same structural formula but are different in spatial arrangement

geometrical: E-Z

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16
Q

Why cant E-Z isomers rotate?

A

Due to restriction of double bond

17
Q

How do you work out if it is an E or Z isomer?

A

E= opposite sides
Z= the same side

  1. Split vertically down the middle of double bond, then focus on the group on the carbon with the highest Ar.
  2. Split horizontally through the double bond, then see if the groups we are focusing on are on the same or different sides.