O Chem Flashcards

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1
Q

2 types of covalent bonds

A

sigma and pi

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2
Q

most electron density in sigma bonds is ..

A

between the nuclei of the 2 atoms

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3
Q

electron density in pi bonds is located

A

above and below the internuclear region

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4
Q

pi bonds are composed of

A

parallel p orbitals

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5
Q

which is stronger - sigma or pi?

A

sigma, almost always

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6
Q

exception to sigma bond stronger rule

A

F2

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7
Q

why is F2 exception to sigma bond rule?

A

small size of atom, leads to nuclei repelling one another

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8
Q

because F2 is composed of pi bonds, it has

A

a weak bond dissociation energy, less than that of Cl2

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9
Q

Alkane C hybridization

A

sp3

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10
Q

alkane bond type

A

sigma bonds

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11
Q

alkene bond type

A

both sigma and pi

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12
Q

hydrogens use - orbitals to form bonds

A

s

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13
Q

bond order in double bonds

A

sigma then pi

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14
Q

bond order in triple bonds

A

sigma, pi, pi

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15
Q

for e- density to overlap e- must have the

A

same spin

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16
Q

long bonds are

A

weaker

17
Q

single bonds are

A

composed of 1 sigma bond between the atoms, and are the longest

18
Q

double bonds are

A

1 sigma and 1 pi bond

19
Q

triple bonds are

A

1 sigma, and 2 pis and are the shortest bonds

20
Q

greater substitution results in a

A

stronger bond

21
Q

HONC 1234 rule

A

H - 1 bond
O 2 bonds
N 3 bonds
C 4 bonds

22
Q

hybrid orbitals are orbitals involved in

A

making bonds between atoms

23
Q

atoms with 4 e- pairs are

A

tetrahedral and have sp3 hybridization

24
Q

atoms with 3 e- pairs are

A

trigonal planar

25
Q

atoms with 2 e- pairs are

A

linear

26
Q

relative acidity of hybrid orbitals

A

sp>sp2>sp3

27
Q

predicted bond angle of sp2

A

120 degrees

28
Q

Z conformation

A

higher priority subs on same side of bond

29
Q

in german that Z word means

A

together

30
Q

E conf

A

higher priority subs on opp side of bond

31
Q

determining higher priority for E v Z

A

higher priority of sub with higher atomic number