moles etc exam questions Flashcards
The student rinses the burette with deionised water before filling with sodium hydroxide solution. State and explain the effect, if any, that this rinsing will have on the value of the titre.
Titre value would increase / larger value
Because the sodium hydroxide solution would be more dilute
A compound contains 40.0% carbon, 6.7% hydrogen and 53.3% oxygen by mass.
Which could be the molecular formula of this compound?
A C2H2O2
B C2H2O
C C2H4O2
D C2HO2
C
When driving a car, a legal limit for ethanol (Mr = 46.0) is 80 mg per 100 cm3 of blood. What is this concentration in mol dm–3?
A 1.74 × 10–1
B 1.74 × 10–2
C 1.74 × 10–3
D 1.74 × 10–4
B
What is the percentage atom economy for the production of ethanol from glucose?
C6H12O6 → 2 C2H5OH + 2 CO2
A 25.6%
B 27.1%
C 51.1%
D 54.2%
C
Nitration of 1.70 g of methyl benzoate (Mr = 136.0) produces methyl 3-nitrobenzoate (Mr = 181.0). The percentage yield is 65.0%
What mass, in g, of methyl 3-nitrobenzoate is produced?
A 0.830
B 1.10
C 1.47
D 2.26
C
Which compound needs the greatest amount of oxygen for the complete combustion of 1 mol of the compound?
A ethanal
B ethanol
C ethane-1,2-diol
D methanol
B
The student noticed that some of the liquid injected into the gas syringe did not vaporise.
Explain the effect that this has on the Mr calculated by the student.
- Calculated Mr value would be greater than actual
- A lower volume would have been recorded
The total uncertainty from two readings and an end point error in using a burette is ± 0.15 cm3
What is the total percentage uncertainty in using the burette in this experiment?
Tick (✓) one box.
0.45%
0.90%
1.34%
0.45%
The equation below represents the complete combustion of butane.
20 cm3 of butane are completely burned in 0.20 dm3 of oxygen.
Which statement is correct?
All volumes are measured at the same temperature and pressure.
A 40 cm3 of carbon dioxide are formed
B 0.065 dm3 of oxygen react
C 70 cm3 of oxygen remain
D 0.50 dm3 of steam are formed
c
The heat released when 1.00 g of ethanol (Mr = 46.0) undergoes complete combustion is 29.8 kJ
What is the heat released by each molecule, in joules, when ethanol undergoes complete combustion?
(the Avogadro constant L = 6.022 × 1023 mol–1)
A 2.28 × 10–18 J
B 4.95 × 10–20 J
C 2.28 × 10–21 J
D 4.95 × 10–23 J
A
Identify the diagram in the figure below that shows the correct relative sizes of the ions in sodium fluoride.
Justify your answer.
B
Both Na+ and F– same electron arrangement
Sodium (ion) has more protons so attracts (outer) electrons closer
The correct value for x is 10.
Suggest a reason for the difference between the experimental value for x and the correct value.
Not heated to constant mass
Suggest how the procedure could be improved, using the same apparatus, to give a more accurate value for x. justify your answer.
Suggestion
Justification
Heat to constant mass
You can be sure all the water has been driven off
Some of the liquid injected did not evaporate because it dripped into the gas syringe nozzle outside the oven.
Explain how this would affect the value of the Mr of Y calculated from the experimental results.
Lower volume recorded
Mr would be greater (than the real Mr)
How many protons are there in 6.0 g of nitrogen gas?
Avogadro constant, L = 6.022 × 1023 mol–1
A
1.3 × 1023
B
9.0 × 1023
C
1.8 × 1024
D
3.6 × 1024
c