Molecular Geometry (VSEPR) Flashcards
VSEPR
The model that describes the molecular geometry of compounds and polyatomic ions is called VSEPR, short for Valence Shell Electron Pair Repulsion. According to this model, the repulsion of electron pairs (bonding pairs and lone pairs) around the central atom of a structure determines the geometry of the structure.
sigma bond
The first covalent bond formed between two atoms is called a sigma (σ) bond.
Pi bond
Any additional bond between the same two atoms is called a pi (π) bond. Triple bond has 2 Pi bonds and one Sigma bond.
why do you only consider sigma bonds not pi bonds when doing stuff?
The electrons of sigma and pi bonds in a double or triple bond do not repel each other since they are attracted by the same two nuclei. Therefore, when in the VSEPR model we make reference to electron pair repulsion, we consider only the lone pairs and sigma bonds.
Structural Pairs
The electron pairs around the central atom that repel each other, and therefore determine the structure of the molecule or polyatomic ion, are called structural pairs. Only lone pairs and sigma bonds are structural pairs.
Electron pair geometry
includes lone pairs and bonds
Molecular geometry
includes bonds, not lone pairs
VSEPR Model
Shows cheese wedge when going in front, wifi signal when going out back and lines for on the same plane. Basically the funky arrow stuff.
Linear
linear
- 2 sigma bonds
- 2 bonds and 3 lone pairs
Trigonal Planar
3 bonds
bent:
- 2 bonds and 1 lone pair
- 2 bonds and 2 lone pairs
tetrahedral
- 4 bonds
trigonal pyramidal
- 3 bonds, 1 lone pair
trigonal bipyramidal
- 5 bonds
seesaw
- 4 bonds, 1 lone pair