Molecular Geometry (VSEPR) Flashcards

1
Q

VSEPR

A

The model that describes the molecular geometry of compounds and polyatomic ions is called VSEPR, short for Valence Shell Electron Pair Repulsion. According to this model, the repulsion of electron pairs (bonding pairs and lone pairs) around the central atom of a structure determines the geometry of the structure.

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2
Q

sigma bond

A

The first covalent bond formed between two atoms is called a sigma (σ) bond.

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3
Q

Pi bond

A

Any additional bond between the same two atoms is called a pi (π) bond. Triple bond has 2 Pi bonds and one Sigma bond.

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4
Q

why do you only consider sigma bonds not pi bonds when doing stuff?

A

The electrons of sigma and pi bonds in a double or triple bond do not repel each other since they are attracted by the same two nuclei. Therefore, when in the VSEPR model we make reference to electron pair repulsion, we consider only the lone pairs and sigma bonds.

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5
Q

Structural Pairs

A

The electron pairs around the central atom that repel each other, and therefore determine the structure of the molecule or polyatomic ion, are called structural pairs. Only lone pairs and sigma bonds are structural pairs.

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6
Q

Electron pair geometry

A

includes lone pairs and bonds

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7
Q

Molecular geometry

A

includes bonds, not lone pairs

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8
Q

VSEPR Model

A

Shows cheese wedge when going in front, wifi signal when going out back and lines for on the same plane. Basically the funky arrow stuff.

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9
Q

Linear

A

linear

  • 2 sigma bonds
  • 2 bonds and 3 lone pairs
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10
Q

Trigonal Planar

A

3 bonds

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11
Q

bent:

A
  • 2 bonds and 1 lone pair

- 2 bonds and 2 lone pairs

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12
Q

tetrahedral

A
  • 4 bonds
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13
Q

trigonal pyramidal

A
  • 3 bonds, 1 lone pair
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14
Q

trigonal bipyramidal

A
  • 5 bonds
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15
Q

seesaw

A
  • 4 bonds, 1 lone pair
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16
Q

t-shaped

A
  • 3 bonds, 2 lone pairs
17
Q

note on electron affinity:

A

if it is positive, that means that energy is needed to add an electron to the neutral atom so it is unstable.

18
Q

isotope notation

A

mass number/ atomic number “X”

the big guy over the small kid

19
Q

period

A

long horizontal guy

20
Q

group

A

downward kid