Molecular And Empirical Formula (OG) Flashcards
Define Molecular Formula
The molecular formula of a compound is the actual number of atoms of the element in that compound
When writing the molecular formula of an organic compound…
We first must draw the carbon atoms then the hydrogen atoms then any other atoms are listed alphabetically.
Define the Empirical formula
The empirical formula is the simplest whole number ratio of the atoms of each element in a compound
How would you calculate the empirical formula?
Divide all numbers in the molecule by the smallest number present if the number is a decimal e.g. 2.5 then multiple all numbers by 2 to get a whole number
Example question: A sample of a hydrocarbon contained 0.48g of carbon and 0.08g of hydrogen. Calculate the empirical formula.
Ar C=12.0, Ar H=1.0
1: Find the moles of carbon and hydrogen (n=m/mr)
2:Then divide both numbers by the smallest number to determine the ratio
Example:
1: carbon- 0.48/12.0=0.04mol and Hydrogen- 0.08/1.0=0.08mol
2: divide both by 0.04 carbon=1 and hydrogen=2
Answer=CH2
Calculate the molecular formula from the empirical formula example:
Relative molecular mass of compound aka Mr=(28.0g/mol)
Empirical formula=CH2—>14.0g/mol
1:Mr of compound/Mr of empirical formula
E.g. 28.0/14.0=2.0
2: Multiple the empirical formula by the answer to get the molecular formula
E.g. CH2x2 is C2H4 aka ethene