Alkenes (OG) Flashcards

1
Q

Define alkene

A

An alkene is an unsaturated hydrocarbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Where are sigma bonds located in an alkene

A

Between carbon atoms and hydrogen atoms they are also located in the double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is a Pi Bond and where is it located

A

a covalent bond formed when ​2 orbitals overlap sideways​ it is located as the second bond in the Double bond of an alkene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Why is there no rotation around the CC double bond?

A

Because of the Pi orbital electron density above and below the single bond, which holds the carbon atoms in place

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Structure of an alkene across the double bond is locked because?

A

The double bond cannot rotate due to its Pi bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Alkenes can form stereoisomers because?

A

The double bond cannot rotate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Alkenes are highly reactive. Why?

A

High electron density of the double bond and because pi bond is easier to break due to them overlapping sideways

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Why is the double bond a region of high electron density?

A

Because the double bond contains two pair of electron for each type of bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What determines how Alkenes react?

A

The region of high electron density aka the double bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Alkenes react through a process called electrophillic addition, define this process.

A

a chemical reaction that occurs when an electrophile attacks a substrate with a multiple bond, resulting in the addition of one or more simple molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Which is more electronegative, hydrogen or halogen atoms

A

Halogen atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Hydrogen halide molecules have a_____________ dipole

A

Permanent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Define electrophile.

A

a chemical species that is attracted to electrons and accepts a pair of electrons to form a bond with a nucleophile

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

When drawing an curly arrow

A

Make sure the arrow starts exactly where the electrons are moving from and ends exactly where they are moving to

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Define Heterolytic fission

A

chemical process that occurs when a covalent bond breaks unevenly, resulting in one atom receiving both electrons from the bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

At the end of electrophilic substitution we have two products. Name them

A
  1. A positively charged intermediate molecule formed from the alkene ( carbocation intermediate ) contains a positively charged carbon atom
    2.Negatively charged halogen ion as both electrons are then on that ion
17
Q

Lastly what happens to the halogen ion

A

It is attracted to the positive carbon in the alkene molecule

18
Q

What intermolecular forces of attraction do they have and why?

A

Van der waals due to non polar bonds

19
Q

Alkenes are not soluble in water, why?

A

Because of non polar bonds

20
Q

What is the most stable kind of carbocation intermediate? Why?

A

Alkyl groups have positive inductive effect so the most stable carbocation is the one bonded to the most other carbon atoms

21
Q

Major products will be formed by which kind of carbocations?

A

Tertiary ( or the most stable ones)