Module 9 Flashcards
Bond Angle of a molecule w/:
1 central atom + 2 other atoms
Electron-Group Structure: Linear
180 degrees
Bond Angle of a molecule w/:
1 central atom + 3 other atoms
Electron-Group Structure: Trigonal Planar
120 degrees
Bond Angle of a molecule w/:
1 central atom + 4 other atoms
Electron-Group Structure: Tetrahedral
109.5 degrees
How to find shape of molecule using VSEPR
- Draw Lewis structure
- Count groups of valence electron
- Pick electron-group structure
- Assign each lone pair group to place in electron group structure
- Assign each bonding electron group to somewhere in the electron-group structure
- Consider bonding groups and structures
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Linear electron group structure
Angle: 180 degrees
2 electron groups
2 bonds
No lone pairs
2 ligands
Bent electron group structure
Angle: 109.5
3-4 (depending on lone pairs) electron groups
1-2 lone pairs
2 bonds
2 ligands
Trigonal planar elecron group structure
Angle: 120 degrees
3 electron groups
Can have lone pairs
3 bonds
3 ligands
Trigonal pyramidal
Angle: 109.5 degrees
4 electron groups
1 lone pair
3 bonds
3 ligands
Tetrahedral
Angle: 109.5 degrees
4 electron groups
No lone pairs
4 bonds
4 ligands
Intermolecular Forces
Hydrogen-bonding
Kind of intermolecular force btwn molecules that:
1) Have 1 of a strongly electronegative molecules O, N, F in each molecule
2) Said electronegative atom in 1 molecule must a) be chemically bonded to a hydrogen, and b) the electronegative atom in the other molecule must have >= 1 lone pair.
Dipole-dipole force
An intermolecular force btwn polar molecules that attracts
London- dispersion forces
An intermolecular force that any 2 molecules exert on each other that attracts
Bigger molecules experience stronger dispersion forces.
Polarizability
Increases with the number of electrons in an atom/molecule
i.e. the more electrons, the better
* You can determine strength of dispersion forces w/ this
Boiling point & Intermolecular forces
The stronger the intermolecular force, the higher the boiling point
Single bond
1 sigma
Double bond
1 sigma + 1 pi
Triple bond
1 sigma + 2 pi
sp^3 hybridization
4 sigma bonds + lone pairs
sp^2 hybridization
3 sigma bonds + lone pairs
sp hybridization
2 sigma bonds + lone pairs
Valence Bond Theory
Hybridization
Can be determined by counting sigma bonds + lone pairs
Polar vs. Nonpolar
Consider shape of molecule and electronegativity of each atom.
Trigonal Bipyramidal
5 electron groups
90 degrees vertical, 120 degrees horizontal
Octahedral
6 electron groups
90 degrees vertical, 90 degrees horizontal
AXE Notation
A - Central Atom
X - ligands
E - lone pairs on central atom
Hybridization
- Count the electron groups (include lone pairs)
- Each one corresponds to s, p, and d orbitals
i.e. 4 electron groups is sp^3,
5 electron groups is sp^3d, etc.
Causes of Deviations from Ideal Bond Angle
- Double, Triple bonds
- Lone pairs
Ion-dipole
Ions and polar molecules exert this on each other.
Comparing boiling points
- ID which w/ strong bonding forces, i.e. metal and binary ionic compounds
- Compare molar masses. The greater, the higher
- W/ similar masses, ID any special intermolecular forces, i.e. dipole and intermolecular forces